Zwitterion enhanced performance in palladium-​phosphine catalyzed ethylene methoxycarbonylation

Santosh Govind Khokarale, Eduardo J. Garcia-Suarez, Jianmin Xiong, Uffe Vie Mentzel, Rasmus Fehrmann, Anders Riisager

Research output: Contribution to journalJournal articleResearchpeer-review

Abstract

Zwitterions were used for the first time as promoters in ethylene methoxycarbonylation for the production of methyl propionate. They were found to improve the catalytic performance of the Pd–phosphine system. The presence of zwitterions could contribute to stabilize transition states and active catalytic Pd intermediates. The beneficial effect of the zwitterions was found to be most pronounced, when low amount of a strong acid (MeSO3H) was used with respect to palladium (below 2 equiv.). Under these conditions, phosphine ligand alkylation and reaction vessel corrosion are also anticipated to be less severe.
Original languageEnglish
JournalCatalysis Communications
Volume44
Pages (from-to)73-75
ISSN1566-7367
DOIs
Publication statusPublished - 2014

Keywords

  • Ethylene
  • Methoxycarbonylation
  • Methyl propionate
  • Palladium
  • Triphenylphosphine
  • Zwitterions

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