Zinc Mediated Tandem Fragmentation-Allylation of Methyl 5-Iodopentofuranosides: Synthesis of Quercitols

Lene Hyldtoft, Robert Madsen

    Research output: Chapter in Book/Report/Conference proceedingArticle in proceedingsResearch

    Abstract

    In the presence of zinc and allyl bromide methyl 5-iodopentofuranosides undergo a tandem fragmentation alkylation to give functionalized dienes. These can undergo ring-closing olefin metathesis to produce cyclohexenes which on dihydroxylation give quercitols.
    Original languageEnglish
    Title of host publicationOMCOS 10
    Place of PublicationVersailles
    PublisherMinistére de l'Education Nationale de la Recherche et de la Technologie
    Publication date1999
    Publication statusPublished - 1999
    Event10th IUPAC Symposium on Organo-Metallic Chemistry Directed Towards Organic Synthesis - Versailles, France
    Duration: 18 Jul 199922 Jul 1999
    Conference number: 10

    Conference

    Conference10th IUPAC Symposium on Organo-Metallic Chemistry Directed Towards Organic Synthesis
    Number10
    CountryFrance
    CityVersailles
    Period18/07/199922/07/1999

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