Zeolite and zeotype-catalysed transformations of biofuranic compounds

Hu Li, Song Yang, Anders Riisager, Ashok Pandey, Rajender S. Sangwan, Shunmugavel Saravanamurugan, Rafael Luque

Research output: Contribution to journalReviewResearchpeer-review

Abstract

Catalytic valorisation of biomass with solid functional materials has been recognised as a promising approach to produce value-added biochemicals and biofuels. Furanic compounds such as 5-hydroxymethylfurfural (HMF), 5-ethoxymethylfurfural, 2,5-dimethylfuran, 2,5-diformylfuran and 2,5-furandicarboxylic acid can be obtained from hexoses and pentoses via selective dehydration and subsequent etherification, hydrogenation, oxidation reactions, which show great potential for industrial applications to replace petroleum-based chemicals and fuels. Zeolite and zeotype micro- and mesoporous materials with tuneable acidity, good thermal stability and shape-selectivity have recently emerged as promising solid catalysts, exhibiting superior catalytic performance to other heterogeneous catalysts. This review focuses on the synthesis of biomass-derived furanic compounds catalysed by zeolitic materials, firstly introducing zeolite-catalysed hydrolysis of di-, oligo- and polysaccharides and isomerization reactions of monomeric sugars. Subsequently, the catalytic dehydration reactions of hexoses and pentoses to obtain HMF and furfural are reported. Particularly, a variety of reaction pathways towards upgrading of the resulting platform furanic molecules to valuable bioproducts over zeolitic materials are discussed.
Original languageEnglish
JournalGreen Chemistry
Volume18
Issue number21
Pages (from-to)5701-5735
Number of pages35
ISSN1463-9262
DOIs
Publication statusPublished - 2016

Fingerprint Dive into the research topics of 'Zeolite and zeotype-catalysed transformations of biofuranic compounds'. Together they form a unique fingerprint.

Cite this