Visualisation and characterisation of heterogeneous bimodal PDMS networks

Frederikke Bahrt, Anders Egede Daugaard, Clemence Fleury, Søren Hvilsted, Anne Ladegaard Skov

Research output: Contribution to journalJournal articleResearchpeer-review

323 Downloads (Pure)


The existence of short-chain domains in heterogeneous bimodal PDMS networks has been confirmed
visually, for the first time, through confocal fluorescence microscopy. The networks were prepared using
a controlled reaction scheme where short PDMS chains were reacted below the gelation point into
hyperbranched structures using a fluorescent silicone compatible cross-linker. The formation of the
hyperbranched structures was confirmed by FTIR, 1H-NMR and size exclusion chromatography (SEC).
The short-chain hyperbranched structures were thereafter mixed with long-chain hyperbranched
structures to form bimodal networks with short-chain domains within a long-chain network. The
average sizes of the short-chain domains were found to vary from 2.1 to 5.7 mm depending on the
short-chain content. The visualised network structure could be correlated thereafter to the elastic
properties, which were determined by rheology. All heterogeneous bimodal networks displayed
significantly lower moduli than mono-modal PDMS elastomers prepared from the long polymer chains.
Low-loss moduli as well as low-sol fractions indicate that low-elastic moduli can be obtained without
compromising the network's structure
Original languageEnglish
JournalR S C Advances
Issue number14
Pages (from-to)6939–6945
Publication statusPublished - 2014

Bibliographical note

This article is published Open Access as part of the RSC's Gold for Gold initiative, licensed under a Creative Commons Attribution 3.0 Unported Licence.

Cite this