Vanadium-Catalyzed Deoxydehydration of Glycerol Without an External Reductant

Allan Robertson Petersen; Lasse Bo Nielsen; Johannes Rytter Dethlefsen; Peter Fristrup

doi:10.1002/cctc.201701049

Vanadium-Catalyzed Deoxydehydration of Glycerol Without an External Reductant

Allan Robertson Petersen^*
, Lasse Bo Nielsen
, Johannes Rytter Dethlefsen
, Peter Fristrup

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

A vanadium‐catalysed deoxydehydration (DODH) of neat glycerol has been developed. Cheap and readily available ammonium metavanadate (NH₄VO₃) affords higher yields of allyl alcohol than the well‐established catalyst methyltrioxorhenium. A study in which deuterium‐labelled glycerol was used was undertaken to further elucidate the dual role of glycerol as both an oxidant and reductant. This study led to the proposal of a metal‐catalysed DODH mechanism for the production of allyl alcohol and a deeper understanding of the formation of the byproducts acrolein and propanal.

Original language	English
Journal	ChemCatChem
Volume	10
Issue number	4
Pages (from-to)	759-778
ISSN	1867-3880
DOIs	https://doi.org/10.1002/cctc.201701049
Publication status	Published - 2018

Keywords

Alcohols
Isotopic labeling
Reaction mechanisms
Rhenium
Vanadium

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title = "Vanadium-Catalyzed Deoxydehydration of Glycerol Without an External Reductant",

abstract = "A vanadium‐catalysed deoxydehydration (DODH) of neat glycerol has been developed. Cheap and readily available ammonium metavanadate (NH4VO3) affords higher yields of allyl alcohol than the well‐established catalyst methyltrioxorhenium. A study in which deuterium‐labelled glycerol was used was undertaken to further elucidate the dual role of glycerol as both an oxidant and reductant. This study led to the proposal of a metal‐catalysed DODH mechanism for the production of allyl alcohol and a deeper understanding of the formation of the byproducts acrolein and propanal.",

keywords = "Alcohols, Isotopic labeling, Reaction mechanisms, Rhenium, Vanadium",

author = "Petersen, \{Allan Robertson\} and Nielsen, \{Lasse Bo\} and Dethlefsen, \{Johannes Rytter\} and Peter Fristrup",

year = "2018",

doi = "10.1002/cctc.201701049",

language = "English",

volume = "10",

pages = "759--778",

journal = "ChemCatChem",

issn = "1867-3880",

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TY - JOUR

T1 - Vanadium-Catalyzed Deoxydehydration of Glycerol Without an External Reductant

AU - Petersen, Allan Robertson

AU - Nielsen, Lasse Bo

AU - Dethlefsen, Johannes Rytter

AU - Fristrup, Peter

PY - 2018

Y1 - 2018

N2 - A vanadium‐catalysed deoxydehydration (DODH) of neat glycerol has been developed. Cheap and readily available ammonium metavanadate (NH4VO3) affords higher yields of allyl alcohol than the well‐established catalyst methyltrioxorhenium. A study in which deuterium‐labelled glycerol was used was undertaken to further elucidate the dual role of glycerol as both an oxidant and reductant. This study led to the proposal of a metal‐catalysed DODH mechanism for the production of allyl alcohol and a deeper understanding of the formation of the byproducts acrolein and propanal.

AB - A vanadium‐catalysed deoxydehydration (DODH) of neat glycerol has been developed. Cheap and readily available ammonium metavanadate (NH4VO3) affords higher yields of allyl alcohol than the well‐established catalyst methyltrioxorhenium. A study in which deuterium‐labelled glycerol was used was undertaken to further elucidate the dual role of glycerol as both an oxidant and reductant. This study led to the proposal of a metal‐catalysed DODH mechanism for the production of allyl alcohol and a deeper understanding of the formation of the byproducts acrolein and propanal.

KW - Alcohols

KW - Isotopic labeling

KW - Reaction mechanisms

KW - Rhenium

KW - Vanadium

U2 - 10.1002/cctc.201701049

DO - 10.1002/cctc.201701049

M3 - Journal article

SN - 1867-3880

VL - 10

SP - 759

EP - 778

JO - ChemCatChem

JF - ChemCatChem

IS - 4

ER -

Vanadium-Catalyzed Deoxydehydration of Glycerol Without an External Reductant

Abstract

Keywords

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