Using Light-Induced Thermocleavage in a Roll-to-Roll Process for Polymer Solar Cells

Frederik C Krebs; Kion Norrman

doi:10.1021/am900858x

Using Light-Induced Thermocleavage in a Roll-to-Roll Process for Polymer Solar Cells

Frederik C Krebs, Kion Norrman

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

We report on the use of intense visible light with a narrow spectral distribution matched to the region where the conjugated polymer material absorbs to selectively heat the active material and induce thermocleavage. We show a full roll-to-roll process, leading to complete large-area polymer solar cell modules using light-induced thermocleavage. The process employs full solution processing in air for all five layers in the device and does not employ indium−tin oxide or vacuum processing. The process steps were carefully analyzed using X-ray photoelectron spectroscopy, time-of-flight secondary ion mass spectrometry, attenuated total reflectance infrared, and transmission/reflection UV−vis techniques.

Original language	English
Journal	A C S Applied Materials and Interfaces
Volume	2
Issue number	3
Pages (from-to)	877-887
ISSN	1944-8244
DOIs	https://doi.org/10.1021/am900858x
Publication status	Published - 2010

Bibliographical note

This work was supported by the Danish
Strategic Research Council (Grants DSF 2104-05-0052
and 2104-07-0022). A patent application covering the inventions described in this article has been filed.

Keywords

Polymer solar cells
Solar energy

Access to Document

10.1021/am900858x

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1 Finished

Polymer Solar Cells for Solar Energy Conversion
Krebs, F. C.
01/01/2008 → 31/12/2013
Project: Research

Cite this

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title = "Using Light-Induced Thermocleavage in a Roll-to-Roll Process for Polymer Solar Cells",

abstract = "We report on the use of intense visible light with a narrow spectral distribution matched to the region where the conjugated polymer material absorbs to selectively heat the active material and induce thermocleavage. We show a full roll-to-roll process, leading to complete large-area polymer solar cell modules using light-induced thermocleavage. The process employs full solution processing in air for all five layers in the device and does not employ indium−tin oxide or vacuum processing. The process steps were carefully analyzed using X-ray photoelectron spectroscopy, time-of-flight secondary ion mass spectrometry, attenuated total reflectance infrared, and transmission/reflection UV−vis techniques.",

keywords = "Polymer solar cells, Solar energy, Plastsolceller, Solenergi",

author = "Krebs, {Frederik C} and Kion Norrman",

note = "This work was supported by the Danish Strategic Research Council (Grants DSF 2104-05-0052 and 2104-07-0022). A patent application covering the inventions described in this article has been filed.",

year = "2010",

doi = "10.1021/am900858x",

language = "English",

volume = "2",

pages = "877--887",

journal = "A C S Applied Materials and Interfaces",

issn = "1944-8244",

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TY - JOUR

T1 - Using Light-Induced Thermocleavage in a Roll-to-Roll Process for Polymer Solar Cells

AU - Krebs, Frederik C

AU - Norrman, Kion

N1 - This work was supported by the Danish Strategic Research Council (Grants DSF 2104-05-0052 and 2104-07-0022). A patent application covering the inventions described in this article has been filed.

PY - 2010

Y1 - 2010

N2 - We report on the use of intense visible light with a narrow spectral distribution matched to the region where the conjugated polymer material absorbs to selectively heat the active material and induce thermocleavage. We show a full roll-to-roll process, leading to complete large-area polymer solar cell modules using light-induced thermocleavage. The process employs full solution processing in air for all five layers in the device and does not employ indium−tin oxide or vacuum processing. The process steps were carefully analyzed using X-ray photoelectron spectroscopy, time-of-flight secondary ion mass spectrometry, attenuated total reflectance infrared, and transmission/reflection UV−vis techniques.

AB - We report on the use of intense visible light with a narrow spectral distribution matched to the region where the conjugated polymer material absorbs to selectively heat the active material and induce thermocleavage. We show a full roll-to-roll process, leading to complete large-area polymer solar cell modules using light-induced thermocleavage. The process employs full solution processing in air for all five layers in the device and does not employ indium−tin oxide or vacuum processing. The process steps were carefully analyzed using X-ray photoelectron spectroscopy, time-of-flight secondary ion mass spectrometry, attenuated total reflectance infrared, and transmission/reflection UV−vis techniques.

KW - Polymer solar cells

KW - Solar energy

KW - Plastsolceller

KW - Solenergi

U2 - 10.1021/am900858x

DO - 10.1021/am900858x

M3 - Journal article

C2 - 20356294

VL - 2

SP - 877

EP - 887

JO - A C S Applied Materials and Interfaces

JF - A C S Applied Materials and Interfaces

SN - 1944-8244

IS - 3

ER -

Using Light-Induced Thermocleavage in a Roll-to-Roll Process for Polymer Solar Cells

Abstract

Bibliographical note

Keywords

Access to Document

Polymer Solar Cells for Solar Energy Conversion

Cite this