Universal Brønsted-Evans-Polanyi Relations for C–C, C–O, C–N, N–O, N–N, and O–O Dissociation Reactions

Shengguang Wang; Burcin Temel; Juan Shen; Glenn Jones; Lars Grabow; Felix Studt; Thomas Bligaard; Frank Abild-Pedersen; Claus H. Christensen; Jens Kehlet Nørskov

doi:10.1007/s10562-010-0477-y

Universal Brønsted-Evans-Polanyi Relations for C–C, C–O, C–N, N–O, N–N, and O–O Dissociation Reactions

Shengguang Wang, Burcin Temel, Juan Shen, Glenn Jones, Lars Grabow, Felix Studt, Thomas Bligaard, Frank Abild-Pedersen, Claus H. Christensen, Jens Kehlet Nørskov

Haldor Topsoe AS

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

It is shown that for all the essential bond forming and bond breaking reactions on metal surfaces, the reactivity of the metal surface correlates linearly with the reaction energy in a single universal relation. Such correlations provide an easy way of establishing trends in reactivity among the different transition metals.

Original language	English
Journal	Catalysis Letters
Volume	141
Issue number	3
Pages (from-to)	370-373
ISSN	1011-372X
DOIs	https://doi.org/10.1007/s10562-010-0477-y
Publication status	Published - 2011

Keywords

Coupling reactions
Stepped surfaces
Density functional theory
BEP relations
Scaling relations
Bond breaking reactions

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10.1007/s10562-010-0477-y

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title = "Universal Br{\o}nsted-Evans-Polanyi Relations for C–C, C–O, C–N, N–O, N–N, and O–O Dissociation Reactions",

abstract = "It is shown that for all the essential bond forming and bond breaking reactions on metal surfaces, the reactivity of the metal surface correlates linearly with the reaction energy in a single universal relation. Such correlations provide an easy way of establishing trends in reactivity among the different transition metals.",

keywords = "Coupling reactions, Stepped surfaces, Density functional theory, BEP relations, Scaling relations, Bond breaking reactions",

author = "Shengguang Wang and Burcin Temel and Juan Shen and Glenn Jones and Lars Grabow and Felix Studt and Thomas Bligaard and Frank Abild-Pedersen and Christensen, {Claus H.} and N{\o}rskov, {Jens Kehlet}",

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doi = "10.1007/s10562-010-0477-y",

language = "English",

volume = "141",

pages = "370--373",

journal = "Catalysis Letters",

issn = "1011-372X",

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T1 - Universal Brønsted-Evans-Polanyi Relations for C–C, C–O, C–N, N–O, N–N, and O–O Dissociation Reactions

AU - Wang, Shengguang

AU - Temel, Burcin

AU - Shen, Juan

AU - Jones, Glenn

AU - Grabow, Lars

AU - Studt, Felix

AU - Bligaard, Thomas

AU - Abild-Pedersen, Frank

AU - Christensen, Claus H.

AU - Nørskov, Jens Kehlet

PY - 2011

Y1 - 2011

N2 - It is shown that for all the essential bond forming and bond breaking reactions on metal surfaces, the reactivity of the metal surface correlates linearly with the reaction energy in a single universal relation. Such correlations provide an easy way of establishing trends in reactivity among the different transition metals.

AB - It is shown that for all the essential bond forming and bond breaking reactions on metal surfaces, the reactivity of the metal surface correlates linearly with the reaction energy in a single universal relation. Such correlations provide an easy way of establishing trends in reactivity among the different transition metals.

KW - Coupling reactions

KW - Stepped surfaces

KW - Density functional theory

KW - BEP relations

KW - Scaling relations

KW - Bond breaking reactions

U2 - 10.1007/s10562-010-0477-y

DO - 10.1007/s10562-010-0477-y

M3 - Journal article

SN - 1011-372X

VL - 141

SP - 370

EP - 373

JO - Catalysis Letters

JF - Catalysis Letters

IS - 3

ER -

Universal Brønsted-Evans-Polanyi Relations for C–C, C–O, C–N, N–O, N–N, and O–O Dissociation Reactions

Abstract

Keywords

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