Understanding the electrocatalysis of oxygen reduction on platinum and its alloys

Ifan E. L. Stephens, Alexander S. Bondarenko, Ulrik Grønbjerg, Ulrik Grønbjerg Vej-Hansen, Jan Rossmeisl, Ib Chorkendorff

Research output: Contribution to journalJournal articleResearchpeer-review

4023 Downloads (Pure)


The high cost of low temperature fuel cells is to a large part dictated by the high loading of Pt required to catalyse the oxygen reduction reaction (ORR). Arguably the most viable route to decrease the Pt loading, and to hence commercialise these devices, is to improve the ORR activity of Pt by alloying it with other metals. In this perspective paper we provide an overview of the fundamentals underlying the reduction of oxygen on platinum and its alloys. We also report the ORR activity of Pt5La for the first time, which shows a 3.5- to 4.5-fold improvement in activity over Pt in the range 0.9 to 0.87 V, respectively. We employ angle resolved X-ray photoelectron spectroscopy and density functional theory calculations to understand the activity of Pt5La.

Original languageEnglish
JournalEnergy & Environmental Science
Issue number5
Pages (from-to)6744-6762
Publication statusPublished - 2012


Dive into the research topics of 'Understanding the electrocatalysis of oxygen reduction on platinum and its alloys'. Together they form a unique fingerprint.

Cite this