Transistor Effects and in situ STM of Redox Molecules at Room Temperature.

T. Albrecht; A. Guckian; Jens Ulstrup; J.G. Vos

doi:10.1109/NANO.2004.1392274

Transistor Effects and in situ STM of Redox Molecules at Room Temperature.

T. Albrecht, A. Guckian, Jens Ulstrup, J.G. Vos

Department of Chemistry

Research output: Chapter in Book/Report/Conference proceeding › Conference abstract in proceedings › Research

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Abstract

Inorganic transition metal complexes were identified as potential candidates for transistor-like behaviour in an electrochemical STM configuration at room temperature. The theoretical background has been established based on condensed matter charge transfer theory. It predicts a distinct increase of the tunnelling current close to the equilibrium potential, i.e. if molecular bridge states are tuned into resonance with the Fermi levels of the enclosing electrodes. The complexes display robust electrochemistry on Au(111) electrode surfaces. STM images at molecular resolution give detailed insight into the surface structure. STS experiments are on the way to probe putative transistor-like behaviour.

Original language	English
Title of host publication	4th IEEE Conference on Nanotechnology, 2004.
Publisher	IEEE
Publication date	2004
ISBN (Print)	0-7803-8536-5
DOIs	https://doi.org/10.1109/NANO.2004.1392274
Publication status	Published - 2004
Event	4th IEEE Conference on Nanotechnology - Munich, Germany Duration: 16 Aug 2004 → 19 Aug 2004 Conference number: 4 https://ieeexplore.ieee.org/xpl/conhome/9589/proceeding

Conference

Conference	4th IEEE Conference on Nanotechnology
Number	4
Country/Territory	Germany
City	Munich
Period	16/08/2004 → 19/08/2004
Internet address	https://ieeexplore.ieee.org/xpl/conhome/9589/proceeding

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Copyright: 2004 IEEE. Personal use of this material is permitted. However, permission to reprint/republish this material for advertising or promotional purposes or for creating new collective works for resale or redistribution to servers or lists, or to reuse any copyrighted component of this work in other works must be obtained from the IEEE

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title = "Transistor Effects and in situ STM of Redox Molecules at Room Temperature.",

abstract = "Inorganic transition metal complexes were identified as potential candidates for transistor-like behaviour in an electrochemical STM configuration at room temperature. The theoretical background has been established based on condensed matter charge transfer theory. It predicts a distinct increase of the tunnelling current close to the equilibrium potential, i.e. if molecular bridge states are tuned into resonance with the Fermi levels of the enclosing electrodes. The complexes display robust electrochemistry on Au(111) electrode surfaces. STM images at molecular resolution give detailed insight into the surface structure. STS experiments are on the way to probe putative transistor-like behaviour.",

author = "T. Albrecht and A. Guckian and Jens Ulstrup and J.G. Vos",

note = "Copyright: 2004 IEEE. Personal use of this material is permitted. However, permission to reprint/republish this material for advertising or promotional purposes or for creating new collective works for resale or redistribution to servers or lists, or to reuse any copyrighted component of this work in other works must be obtained from the IEEE; 4th IEEE Conference on Nanotechnology, NANO 2004 ; Conference date: 16-08-2004 Through 19-08-2004",

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AU - Guckian, A.

AU - Ulstrup, Jens

AU - Vos, J.G.

N1 - Conference code: 4

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N2 - Inorganic transition metal complexes were identified as potential candidates for transistor-like behaviour in an electrochemical STM configuration at room temperature. The theoretical background has been established based on condensed matter charge transfer theory. It predicts a distinct increase of the tunnelling current close to the equilibrium potential, i.e. if molecular bridge states are tuned into resonance with the Fermi levels of the enclosing electrodes. The complexes display robust electrochemistry on Au(111) electrode surfaces. STM images at molecular resolution give detailed insight into the surface structure. STS experiments are on the way to probe putative transistor-like behaviour.

AB - Inorganic transition metal complexes were identified as potential candidates for transistor-like behaviour in an electrochemical STM configuration at room temperature. The theoretical background has been established based on condensed matter charge transfer theory. It predicts a distinct increase of the tunnelling current close to the equilibrium potential, i.e. if molecular bridge states are tuned into resonance with the Fermi levels of the enclosing electrodes. The complexes display robust electrochemistry on Au(111) electrode surfaces. STM images at molecular resolution give detailed insight into the surface structure. STS experiments are on the way to probe putative transistor-like behaviour.

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DO - 10.1109/NANO.2004.1392274

M3 - Conference abstract in proceedings

SN - 0-7803-8536-5

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ER -

Transistor Effects and in situ STM of Redox Molecules at Room Temperature.

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