Towards a methanol economy based on homogeneous catalysis: methanol to H2 and CO2 to methanol

E. Alberico, Martin Nielsen

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Abstract

The possibility to implement both the exhaustive dehydrogenation of aqueous methanol to hydrogen and CO2 and the reverse reaction, the hydrogenation of CO2 to methanol and water, may pave the way to a methanol based economy as part of a promising renewable energy system. Recently, homogeneous catalytic systems have been reported which are able to promote either one or the other of the two reactions under mild conditions. Here, we review and discuss these developments.
Original languageEnglish
JournalChemical Communications
Volume51
Issue number31
Pages (from-to)6714-6725
Number of pages12
ISSN1359-7345
DOIs
Publication statusPublished - 2015

Bibliographical note

This article is published Open Access as part of the RSC's Gold for Gold initiative, licensed under a Creative Commons Attribution 3.0 Unported Licence.

Cite this

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abstract = "The possibility to implement both the exhaustive dehydrogenation of aqueous methanol to hydrogen and CO2 and the reverse reaction, the hydrogenation of CO2 to methanol and water, may pave the way to a methanol based economy as part of a promising renewable energy system. Recently, homogeneous catalytic systems have been reported which are able to promote either one or the other of the two reactions under mild conditions. Here, we review and discuss these developments.",
author = "E. Alberico and Martin Nielsen",
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Towards a methanol economy based on homogeneous catalysis: methanol to H2 and CO2 to methanol. / Alberico, E.; Nielsen, Martin.

In: Chemical Communications, Vol. 51, No. 31, 2015, p. 6714-6725.

Research output: Contribution to journalJournal articleResearchpeer-review

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AU - Alberico, E.

AU - Nielsen, Martin

N1 - This article is published Open Access as part of the RSC's Gold for Gold initiative, licensed under a Creative Commons Attribution 3.0 Unported Licence.

PY - 2015

Y1 - 2015

N2 - The possibility to implement both the exhaustive dehydrogenation of aqueous methanol to hydrogen and CO2 and the reverse reaction, the hydrogenation of CO2 to methanol and water, may pave the way to a methanol based economy as part of a promising renewable energy system. Recently, homogeneous catalytic systems have been reported which are able to promote either one or the other of the two reactions under mild conditions. Here, we review and discuss these developments.

AB - The possibility to implement both the exhaustive dehydrogenation of aqueous methanol to hydrogen and CO2 and the reverse reaction, the hydrogenation of CO2 to methanol and water, may pave the way to a methanol based economy as part of a promising renewable energy system. Recently, homogeneous catalytic systems have been reported which are able to promote either one or the other of the two reactions under mild conditions. Here, we review and discuss these developments.

U2 - 10.1039/c4cc09471a

DO - 10.1039/c4cc09471a

M3 - Journal article

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JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

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