Time-resolved resonance Raman spectra of the lowest excited triplet state of all-trans-2,4,6-octatriene, alloocimene and neo-alloocimene

Frans W. Langkilde, Niels-Henrik Jensen, Robert Walter Wilbrandt

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    Abstract

    The lowest excited triplet states of all-trans-2,4,6-octatriene, alloocimene and neo-alloocimene have been studied by time-resolved resonance Raman spectroscopy. The spectra showed bands at 1574, 1264, 1252, 1205, and 1136 cm−1 for octatriene, at 1560 cm−1 for alloocimene, and at 1559 cm−1 for the-alloocimene. Possible implications for the relaxed triplet geometries are discussed.
    Original languageEnglish
    JournalChemical Physics Letters
    Volume118
    Issue number5
    Pages (from-to)486-492
    ISSN0009-2614
    Publication statusPublished - 1985

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