Thermodynamic comparison of three small-scale gas liquefaction systems

Natural gas liquefaction systems are based on refrigeration cycles, which can be subdivided into the cascade, mixed refrigerant and expander-based processes. They differ by their configurations, components and working fluids, and have therefore various operating conditions and equipment inventory. The present work investigates three configurations suitable for small-scale applications because of their simplicity and compactness: the single-mixed refrigerant, single and dual reverse Brayton cycles. The impact of different feed compositions and refrigerant properties is analysed. A detailed assessment of the energy and exergy owsis conducted, and the most promising cycle layouts are identified by performing multi-objective optimisation procedures. The findings illustrate the resulting trade-offs between the system performance and size indifferent operating conditions. Mixed-refrigerant processes prove to be more efficient (1000-2000 kJ/kgLNG) than expander-based ones (2500-5000 kJ/kgLNG) over larger ranges of operating conditions, at the expense of a greater system complexity and higher thermal conductance (250-500kW/K against 80-160 kW/K). The results show that the use of different thermodynamic models leads to relative deviations of up to 1% for the power consumption and 20% for the network conductance. Particular caution should thus be exercised when extrapolating the results of process models to the design of actual gas liquefaction systems.