Thermodynamic assessment of the CoOx-CrO1.5 system

Jonas Allan Östby, Ming Chen

    Research output: Contribution to journalJournal articleResearchpeer-review

    Abstract

    By application of the CALPHAD method, a consistent set of thermodynamic model parameters is optimized for the oxide phases in the Co–Cr–O system. Cobalt chromium spinel is described as a normal spinel at room temperature and with cation redistribution at high temperature. All the solid oxide solution phases are described using the compound energy model, and the liquid phase is described using the two-sublattice model for ionic liquids. Calculated phase diagrams are presented, and values for the thermodynamic properties are compared with experimental data.
    Original languageEnglish
    JournalJournal of Alloys and Compounds
    Volume485
    Issue number1-2
    Pages (from-to)427-434
    ISSN0925-8388
    DOIs
    Publication statusPublished - 2009

    Keywords

    • Solid Oxide Fuel Cells
    • Fuel Cells and hydrogen

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