Thermal stability and thermodynamic properties of hybrid proton conducting polyaryletherketones

Debora Marani; M.L.  Di Vona; E. Traversa; S. Licoccia; I.  Beurroies; P. L.  Llewellyn; P.  Knauth

doi:10.1021/jp062085h

Thermal stability and thermodynamic properties of hybrid proton conducting polyaryletherketones

Debora Marani, M.L. Di Vona, E. Traversa, S. Licoccia, I. Beurroies, P. L. Llewellyn, P. Knauth

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

The thermal and structural stability of sulfonated cross-linked PEEK (polyether ether ketone) and its silicon containing class II hybrid derivatives were characterized by combination of mass spectrometry, infrared spectroscopy, X-ray diffraction, thermogravimetric analysis, and differential scanning calorimetry. Thermodynamic properties of the hybrids were determined, including glass-transition temperature, degree of crystallinity, and thermal stability. The decomposition processes of the hybrid polymers could be consistently interpreted and their energetics quantitatively determined. The introduction of inorganic silanol moieties improves the thermal stability compared to sulfonated products.

Original language	English
Journal	Journal of Physical Chemistry Part B: Condensed Matter, Materials, Surfaces, Interfaces & Biophysical
Volume	110
Pages (from-to)	15817-15823
ISSN	1520-6106
DOIs	https://doi.org/10.1021/jp062085h
Publication status	Published - 2006
Externally published	Yes

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title = "Thermal stability and thermodynamic properties of hybrid proton conducting polyaryletherketones",

abstract = "The thermal and structural stability of sulfonated cross-linked PEEK (polyether ether ketone) and its silicon containing class II hybrid derivatives were characterized by combination of mass spectrometry, infrared spectroscopy, X-ray diffraction, thermogravimetric analysis, and differential scanning calorimetry. Thermodynamic properties of the hybrids were determined, including glass-transition temperature, degree of crystallinity, and thermal stability. The decomposition processes of the hybrid polymers could be consistently interpreted and their energetics quantitatively determined. The introduction of inorganic silanol moieties improves the thermal stability compared to sulfonated products.",

author = "Debora Marani and {Di Vona}, M.L. and E. Traversa and S. Licoccia and I. Beurroies and Llewellyn, {P. L.} and P. Knauth",

year = "2006",

doi = "10.1021/jp062085h",

language = "English",

volume = "110",

pages = "15817--15823",

journal = "Journal of Physical Chemistry Part B: Condensed Matter, Materials, Surfaces, Interfaces & Biophysical",

issn = "1520-6106",

publisher = "American Chemical Society",

}

Thermal stability and thermodynamic properties of hybrid proton conducting polyaryletherketones. / Marani, Debora; Di Vona, M.L. ; Traversa, E. et al.
In: Journal of Physical Chemistry Part B: Condensed Matter, Materials, Surfaces, Interfaces & Biophysical, Vol. 110, 2006, p. 15817-15823.

Research output: Contribution to journal › Journal article › Research › peer-review

TY - JOUR

T1 - Thermal stability and thermodynamic properties of hybrid proton conducting polyaryletherketones

AU - Marani, Debora

AU - Di Vona, M.L.

AU - Traversa, E.

AU - Licoccia, S.

AU - Beurroies, I.

AU - Llewellyn, P. L.

AU - Knauth, P.

PY - 2006

Y1 - 2006

N2 - The thermal and structural stability of sulfonated cross-linked PEEK (polyether ether ketone) and its silicon containing class II hybrid derivatives were characterized by combination of mass spectrometry, infrared spectroscopy, X-ray diffraction, thermogravimetric analysis, and differential scanning calorimetry. Thermodynamic properties of the hybrids were determined, including glass-transition temperature, degree of crystallinity, and thermal stability. The decomposition processes of the hybrid polymers could be consistently interpreted and their energetics quantitatively determined. The introduction of inorganic silanol moieties improves the thermal stability compared to sulfonated products.

AB - The thermal and structural stability of sulfonated cross-linked PEEK (polyether ether ketone) and its silicon containing class II hybrid derivatives were characterized by combination of mass spectrometry, infrared spectroscopy, X-ray diffraction, thermogravimetric analysis, and differential scanning calorimetry. Thermodynamic properties of the hybrids were determined, including glass-transition temperature, degree of crystallinity, and thermal stability. The decomposition processes of the hybrid polymers could be consistently interpreted and their energetics quantitatively determined. The introduction of inorganic silanol moieties improves the thermal stability compared to sulfonated products.

U2 - 10.1021/jp062085h

DO - 10.1021/jp062085h

M3 - Journal article

SN - 1520-6106

VL - 110

SP - 15817

EP - 15823

JO - Journal of Physical Chemistry Part B: Condensed Matter, Materials, Surfaces, Interfaces & Biophysical

JF - Journal of Physical Chemistry Part B: Condensed Matter, Materials, Surfaces, Interfaces & Biophysical

ER -

Thermal stability and thermodynamic properties of hybrid proton conducting polyaryletherketones

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