Thermal decomposition of lanthanum(III) butyrate in argon atmosphere

Jean-Claude Grivel, Zhao Yue, Tang Xiao, Pallewatta G A P Pallewatta, A. Watenphul, M.v. Zimmermann

Research output: Contribution to journalJournal articleResearchpeer-review

Abstract

The thermal decomposition of La(C3H7CO2)3·xH2O (x≈0.82) was studied in argon during heating at 5K/min. After the loss of bound H2O, the anhydrous butyrate presents at 135°C a phase transition to a mesophase, which turns to an isotropic liquid at 180°C. The decomposition of the anhydrous butyrate is associated to a solidification process. The final decomposition to La2O3 takes place via two intermediate products: La2O(C3H7CO2)4 and La2O2CO3 with release of CO2 and the symmetrical ketone C3H7COC3H7.

Original languageEnglish
JournalThermochimica Acta
Volume566
Pages (from-to)112-117
ISSN0040-6031
DOIs
Publication statusPublished - 2013

Keywords

  • Lanthanum
  • Butyrate
  • Thermal decomposition
  • TG/DTA
  • FTIR

Cite this

Grivel, J-C., Yue, Z., Xiao, T., Pallewatta, P. G. A. P., Watenphul, A., & Zimmermann, M. V. (2013). Thermal decomposition of lanthanum(III) butyrate in argon atmosphere. Thermochimica Acta, 566, 112-117. https://doi.org/10.1016/j.tca.2013.05.016