Thermal annealing in neutron-irradiated tribromobenzenes

K.E. Siekierska; A. Halpern; A. G. Maddock

doi:10.1039/J19680001645

Thermal annealing in neutron-irradiated tribromobenzenes

K.E. Siekierska
, A. Halpern
, A. G. Maddock

Institute of Nuclear Research
University of Cambridge

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

The distribution of 82Br among various products in neutron-irradiated isomers of tribromobenzene has been investigated, and the effect of thermal annealing examined. Reversed-phase partition chromatography was employed for the determination of radioactive organic products, and atomic bromine in the crystals was estimated by means of the 1,2-dibromoethylene exchange technique. The results suggest that, as a consequence of nuclear events, quite a number of different reactions occur whereas the principal annealing reaction is a recombination of atomic bromine with a dibromophenyl radical.

Original language	English
Journal	Journal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry
Pages (from-to)	1645-1651
ISSN	0022-4944
DOIs	https://doi.org/10.1039/J19680001645
Publication status	Published - 1968

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title = "Thermal annealing in neutron-irradiated tribromobenzenes",

abstract = "The distribution of 82Br among various products in neutron-irradiated isomers of tribromobenzene has been investigated, and the effect of thermal annealing examined. Reversed-phase partition chromatography was employed for the determination of radioactive organic products, and atomic bromine in the crystals was estimated by means of the 1,2-dibromoethylene exchange technique. The results suggest that, as a consequence of nuclear events, quite a number of different reactions occur whereas the principal annealing reaction is a recombination of atomic bromine with a dibromophenyl radical.",

author = "K.E. Siekierska and A. Halpern and Maddock, \{A. G.\}",

year = "1968",

doi = "10.1039/J19680001645",

language = "English",

pages = "1645--1651",

journal = "Journal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry",

issn = "0022-4944",

publisher = "Chemical Society",

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T1 - Thermal annealing in neutron-irradiated tribromobenzenes

AU - Siekierska, K.E.

AU - Halpern, A.

AU - Maddock, A. G.

PY - 1968

Y1 - 1968

N2 - The distribution of 82Br among various products in neutron-irradiated isomers of tribromobenzene has been investigated, and the effect of thermal annealing examined. Reversed-phase partition chromatography was employed for the determination of radioactive organic products, and atomic bromine in the crystals was estimated by means of the 1,2-dibromoethylene exchange technique. The results suggest that, as a consequence of nuclear events, quite a number of different reactions occur whereas the principal annealing reaction is a recombination of atomic bromine with a dibromophenyl radical.

AB - The distribution of 82Br among various products in neutron-irradiated isomers of tribromobenzene has been investigated, and the effect of thermal annealing examined. Reversed-phase partition chromatography was employed for the determination of radioactive organic products, and atomic bromine in the crystals was estimated by means of the 1,2-dibromoethylene exchange technique. The results suggest that, as a consequence of nuclear events, quite a number of different reactions occur whereas the principal annealing reaction is a recombination of atomic bromine with a dibromophenyl radical.

U2 - 10.1039/J19680001645

DO - 10.1039/J19680001645

M3 - Journal article

SN - 0022-4944

SP - 1645

EP - 1651

JO - Journal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry

JF - Journal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry

ER -

Thermal annealing in neutron-irradiated tribromobenzenes

Abstract

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