TY - JOUR
T1 - Thermal annealing in neutron-irradiated tribromobenzenes
AU - Siekierska, K.E.
AU - Halpern, A.
AU - Maddock, A. G.
PY - 1968
Y1 - 1968
N2 - The distribution of 82Br among various products in neutron-irradiated isomers of tribromobenzene has been investigated, and the effect of thermal annealing examined. Reversed-phase partition chromatography was employed for the determination of radioactive organic products, and atomic bromine in the crystals was estimated by means of the 1,2-dibromoethylene exchange technique. The results suggest that, as a consequence of nuclear events, quite a number of different reactions occur whereas the principal annealing reaction is a recombination of atomic bromine with a dibromophenyl radical.
AB - The distribution of 82Br among various products in neutron-irradiated isomers of tribromobenzene has been investigated, and the effect of thermal annealing examined. Reversed-phase partition chromatography was employed for the determination of radioactive organic products, and atomic bromine in the crystals was estimated by means of the 1,2-dibromoethylene exchange technique. The results suggest that, as a consequence of nuclear events, quite a number of different reactions occur whereas the principal annealing reaction is a recombination of atomic bromine with a dibromophenyl radical.
U2 - 10.1039/J19680001645
DO - 10.1039/J19680001645
M3 - Journal article
SN - 0022-4944
SP - 1645
EP - 1651
JO - Journal of the Chemical Society. A. Inorganic, physical, theoretical
JF - Journal of the Chemical Society. A. Inorganic, physical, theoretical
ER -