The Structure of the Solid Electrolyte Li1.6Ag0.4So4 at 565 degree C

L. Nilsson; N. H. Andersen; Jørgen Kjems

doi:10.1016/0167-2738(82)90041-8

The Structure of the Solid Electrolyte Li1.6Ag0.4So4 at 565 degree C

L. Nilsson
, N. H. Andersen
, Jørgen Kjems

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

The structure of the high-temperature solid solution Li1.6Ag0.4SO4 has been determined from neutron and X-ray powder diffraction data. The sulphate groups form a fcc lattice where the lithium ions are found to occupy the ±(1/4, 1/4, 1/4) tetrahedral sites. The silver ions partly occupy the same sites and partly the larger (½, ½, ½) octahedral site. The results strongly support earlier conclusions for the fcc phase of Li2SO4. Exceptionally high temperature factors are found. The consistency of the structural model with other characteristic properties of the high-temperature fcc phase is briefly discussed.

Original language	English
Journal	Solid State Ionics
Volume	6
Issue number	3
Pages (from-to)	209-214
ISSN	0167-2738
DOIs	https://doi.org/10.1016/0167-2738(82)90041-8
Publication status	Published - 1982

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title = "The Structure of the Solid Electrolyte Li1.6Ag0.4So4 at 565 degree C",

abstract = "The structure of the high-temperature solid solution Li1.6Ag0.4SO4 has been determined from neutron and X-ray powder diffraction data. The sulphate groups form a fcc lattice where the lithium ions are found to occupy the ±(1/4, 1/4, 1/4) tetrahedral sites. The silver ions partly occupy the same sites and partly the larger (½, ½, ½) octahedral site. The results strongly support earlier conclusions for the fcc phase of Li2SO4. Exceptionally high temperature factors are found. The consistency of the structural model with other characteristic properties of the high-temperature fcc phase is briefly discussed.",

author = "L. Nilsson and Andersen, \{N. H.\} and J{\o}rgen Kjems",

year = "1982",

doi = "10.1016/0167-2738(82)90041-8",

language = "English",

volume = "6",

pages = "209--214",

journal = "Solid State Ionics",

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T1 - The Structure of the Solid Electrolyte Li1.6Ag0.4So4 at 565 degree C

AU - Nilsson, L.

AU - Andersen, N. H.

AU - Kjems, Jørgen

PY - 1982

Y1 - 1982

N2 - The structure of the high-temperature solid solution Li1.6Ag0.4SO4 has been determined from neutron and X-ray powder diffraction data. The sulphate groups form a fcc lattice where the lithium ions are found to occupy the ±(1/4, 1/4, 1/4) tetrahedral sites. The silver ions partly occupy the same sites and partly the larger (½, ½, ½) octahedral site. The results strongly support earlier conclusions for the fcc phase of Li2SO4. Exceptionally high temperature factors are found. The consistency of the structural model with other characteristic properties of the high-temperature fcc phase is briefly discussed.

AB - The structure of the high-temperature solid solution Li1.6Ag0.4SO4 has been determined from neutron and X-ray powder diffraction data. The sulphate groups form a fcc lattice where the lithium ions are found to occupy the ±(1/4, 1/4, 1/4) tetrahedral sites. The silver ions partly occupy the same sites and partly the larger (½, ½, ½) octahedral site. The results strongly support earlier conclusions for the fcc phase of Li2SO4. Exceptionally high temperature factors are found. The consistency of the structural model with other characteristic properties of the high-temperature fcc phase is briefly discussed.

U2 - 10.1016/0167-2738(82)90041-8

DO - 10.1016/0167-2738(82)90041-8

M3 - Journal article

SN - 0167-2738

VL - 6

SP - 209

EP - 214

JO - Solid State Ionics

JF - Solid State Ionics

IS - 3

ER -

The Structure of the Solid Electrolyte Li1.6Ag0.4So4 at 565 degree C

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