Temperature effects in a nonlinear model of monolayer Scheibe aggregates

Ole Bang, Peter Leth Christiansen, F. If, Kim Rasmussen, Y. B. Gaididei

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    Abstract

    A nonlinear dynamical model of molecular monolayers arranged in Scheibe aggregates is derived from a proper Hamiltonian. Thermal fluctuations of the phonons are included. The resulting equation for the excitons is the two dimensional nonlinear Schrodinger equation with noise. Two limits of the complicated spectrum of the noise are considered: time independent, spatially white noise, simply corresponding to disorder in the arrangement of the molecules, and pure white noise. Parameter values are found by comparison with experiments by Mobius and Kuhn [Isr. J. Chem. 18, 375 (1979)] and order of magnitude estimates given where experiments are not available. The temperature dependent coherence time is found from numerical simulations. Experiments show that the excitons stay coherent during their life-time. This is in correspondence with the model at temperatures lower than 3 K. To increase this limiting temperature it is found that the dipole-dipole coupling and the exciton-phonon coupling must be decreased significantly.
    Original languageEnglish
    JournalPhysical Review E. Statistical, Nonlinear, and Soft Matter Physics
    Volume49
    Issue number5
    Pages (from-to)4627-4636
    ISSN1063-651X
    DOIs
    Publication statusPublished - 1994

    Bibliographical note

    Copyright (1994) by the American Physical Society.

    Keywords

    • ASSEMBLIES
    • ENERGY-TRANSFER
    • EXCITONS
    • DECAY

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