Temperature and Pressure Dependence of the Reaction S plus CS (+M) -> CS2 (+M)

Peter Glarborg; Paul Marshall; Juergen Troe

doi:10.1021/Jp5121492

Temperature and Pressure Dependence of the Reaction S plus CS (+M) -> CS2 (+M)

Peter Glarborg, Paul Marshall, Juergen Troe

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

Experimental data for the unimolecular decomposition of CS2 from the literature are analyzed by unimolecular rate theory with the goal of obtaining rate constants for the reverse reaction S + CS (+M) -> CS₂(+M) over wide temperature and pressure ranges. The results constitute an important input for the kinetic modeling of CS2 oxidation. CS₂ dissociation proceeds as a spin-forbidden process whose detailed properties are still not well understood. The role of the singlet triplet transition involved is discussed.

Original language	English
Journal	Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory
Volume	119
Issue number	28
Pages (from-to)	7277-7281
ISSN	1089-5639
DOIs	https://doi.org/10.1021/Jp5121492
Publication status	Published - 2015

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title = "Temperature and Pressure Dependence of the Reaction S plus CS (+M) -> CS2 (+M)",

abstract = "Experimental data for the unimolecular decomposition of CS2 from the literature are analyzed by unimolecular rate theory with the goal of obtaining rate constants for the reverse reaction S + CS (+M) -> CS2 (+M) over wide temperature and pressure ranges. The results constitute an important input for the kinetic modeling of CS2 oxidation. CS2 dissociation proceeds as a spin-forbidden process whose detailed properties are still not well understood. The role of the singlet triplet transition involved is discussed.",

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AU - Glarborg, Peter

AU - Marshall, Paul

AU - Troe, Juergen

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N2 - Experimental data for the unimolecular decomposition of CS2 from the literature are analyzed by unimolecular rate theory with the goal of obtaining rate constants for the reverse reaction S + CS (+M) -> CS2 (+M) over wide temperature and pressure ranges. The results constitute an important input for the kinetic modeling of CS2 oxidation. CS2 dissociation proceeds as a spin-forbidden process whose detailed properties are still not well understood. The role of the singlet triplet transition involved is discussed.

AB - Experimental data for the unimolecular decomposition of CS2 from the literature are analyzed by unimolecular rate theory with the goal of obtaining rate constants for the reverse reaction S + CS (+M) -> CS2 (+M) over wide temperature and pressure ranges. The results constitute an important input for the kinetic modeling of CS2 oxidation. CS2 dissociation proceeds as a spin-forbidden process whose detailed properties are still not well understood. The role of the singlet triplet transition involved is discussed.

U2 - 10.1021/Jp5121492

DO - 10.1021/Jp5121492

M3 - Journal article

SN - 1089-5639

VL - 119

SP - 7277

EP - 7281

JO - Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory

JF - Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory

IS - 28

ER -

Temperature and Pressure Dependence of the Reaction S plus CS (+M) -> CS2 (+M)

Abstract

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