Techno-economic Optimization and working fluid selection of a biogas-based dual-loop bi-evaporator ejector cooling cycle involving power-to-hydrogen and water facilities

Biogas-fueled decentralized energy systems featuring gas turbines emerge as pivotal players in the quest for more adaptable and eco-friendly energy solutions. This study presents the design of a cutting-edge multigeneration system that harnesses the potential of a gas turbine coupled with ejector-driven dual-loop bi-evaporator technology, reverse osmosis desalination, proton exchange membrane electrolysis, and an organic Rankine cycle. The research encompasses an extensive sensitivity analysis and deploys a genetic algorithm-based optimization technique. Through meticulous Optimization, the system achieves remarkable outcomes, including electricity generation, cooling capacity, heating capacity, desalinated water production, and hydrogen yield, measured at 957.3 kW, 231.4 kW, 272.3 kW, 7.336 kg/s, and 0.99 kg/h, respectively. Notably, this performance surpasses the base case by 2% and 8.9%, yielding exergy efficiency and total unit cost improvements of 33.3% and 16.4 $/GJ. Among the critical decisions made was selecting an organic working fluid for the organic Rankine cycle. Through rigorous evaluation, isobutene emerged as the optimal choice, demonstrating significantly improved output power compared to alternatives. Isobutane as the working fluid led to a substantial increase in overall exergy efficiency and a resultant total unit cost of 18.06 $/GJ, accompanied by an impressive 23.48% exergy efficiency.