Techniques in Gas-Phase Thermolyses. Part 6. Pulse Pyrolysis: Gas Kinetic Studies in an Inductively Heated Flow Reactor

Helge Egsgaard, P. Bo, Lars Carlsen

    Research output: Contribution to journalJournal articleResearchpeer-review

    Abstract

    A prototype of an inductively heated flow reactor for gas kinetic studies is presented. The applicability of the system, which is based on a direct coupling between the reactor and the ion source of a mass spectrometer, is illustrated by investigations of a series of simple bond fission reactions. The method permits the direct determination of low-pressure rate constants, the transformation to high-pressure values, and correspondingly evaluation of activation parameters, being derived by means of an empirical effective temperature approach.
    Original languageEnglish
    JournalJournal of Analytical and Applied Pyrolysis
    Volume8
    Pages (from-to)3-14
    ISSN0165-2370
    Publication statusPublished - 1985

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