TY - JOUR
T1 - Techniques in Gas-Phase Thermolyses. Part 6. Pulse Pyrolysis: Gas Kinetic Studies in an Inductively Heated Flow Reactor
AU - Egsgaard, Helge
AU - Bo, P.
AU - Carlsen, Lars
PY - 1985
Y1 - 1985
N2 - A prototype of an inductively heated flow reactor for gas kinetic studies is presented. The applicability of the system, which is based on a direct coupling between the reactor and the ion source of a mass spectrometer, is illustrated by investigations of a series of simple bond fission reactions. The method permits the direct determination of low-pressure rate constants, the transformation to high-pressure values, and correspondingly evaluation of activation parameters, being derived by means of an empirical effective temperature approach.
AB - A prototype of an inductively heated flow reactor for gas kinetic studies is presented. The applicability of the system, which is based on a direct coupling between the reactor and the ion source of a mass spectrometer, is illustrated by investigations of a series of simple bond fission reactions. The method permits the direct determination of low-pressure rate constants, the transformation to high-pressure values, and correspondingly evaluation of activation parameters, being derived by means of an empirical effective temperature approach.
U2 - 10.1016/0165-2370(85)80010-3
DO - 10.1016/0165-2370(85)80010-3
M3 - Journal article
SN - 0165-2370
VL - 8
SP - 3
EP - 14
JO - Journal of Analytical and Applied Pyrolysis
JF - Journal of Analytical and Applied Pyrolysis
IS - C
ER -