Synthesis and Structure of Cyclic Hexanuclear Oxo-alkoxo-carboxylatoniobium(IV) Complexes

Bee Lean Ooi; Inger Søtofte; Jagadese J. Vittal

Synthesis and Structure of Cyclic Hexanuclear Oxo-alkoxo-carboxylatoniobium(IV) Complexes

Bee Lean Ooi, Inger Søtofte, Jagadese J. Vittal

Department of Chemistry

Research output: Contribution to journal › Journal article › Communication

Abstract

The reaction of trichloroacetic acid and trfluoroacetic acid with zinc-reduced niobium pentachloride in ethanolic solutions affords the compounds Nb6(mu2-O)3(mu2-O2CCX3)6(mu2-OC2H5)6(OC2H5)6 (X = Cl, F respectively). A cyclic hexanuclear structure is revealed by X-ray crystallographic studies.

Original language	English
Journal	Inorganica Chimica Acta
Volume	357
Pages (from-to)	625-629
ISSN	0020-1693
Publication status	Published - 2004

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title = "Synthesis and Structure of Cyclic Hexanuclear Oxo-alkoxo-carboxylatoniobium(IV) Complexes",

abstract = "The reaction of trichloroacetic acid and trfluoroacetic acid with zinc-reduced niobium pentachloride in ethanolic solutions affords the compounds Nb6(mu2-O)3(mu2-O2CCX3)6(mu2-OC2H5)6(OC2H5)6 (X = Cl, F respectively). A cyclic hexanuclear structure is revealed by X-ray crystallographic studies.",

author = "Ooi, {Bee Lean} and Inger S{\o}tofte and Vittal, {Jagadese J.}",

year = "2004",

language = "English",

volume = "357",

pages = "625--629",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier",

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TY - JOUR

T1 - Synthesis and Structure of Cyclic Hexanuclear Oxo-alkoxo-carboxylatoniobium(IV) Complexes

AU - Ooi, Bee Lean

AU - Søtofte, Inger

AU - Vittal, Jagadese J.

PY - 2004

Y1 - 2004

N2 - The reaction of trichloroacetic acid and trfluoroacetic acid with zinc-reduced niobium pentachloride in ethanolic solutions affords the compounds Nb6(mu2-O)3(mu2-O2CCX3)6(mu2-OC2H5)6(OC2H5)6 (X = Cl, F respectively). A cyclic hexanuclear structure is revealed by X-ray crystallographic studies.

AB - The reaction of trichloroacetic acid and trfluoroacetic acid with zinc-reduced niobium pentachloride in ethanolic solutions affords the compounds Nb6(mu2-O)3(mu2-O2CCX3)6(mu2-OC2H5)6(OC2H5)6 (X = Cl, F respectively). A cyclic hexanuclear structure is revealed by X-ray crystallographic studies.

M3 - Journal article

SN - 0020-1693

VL - 357

SP - 625

EP - 629

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

ER -