Synergistic coconversion of refinery fuel oil and methanol over H-ZSM-5 catalyst for enhanced production of light olefins

Mohammad Ghashghaee; Samira Shirvani; Mehdi Ghambarian; Søren Kegnæs

doi:10.1021/acs.energyfuels.9b00347

Synergistic coconversion of refinery fuel oil and methanol over H-ZSM-5 catalyst for enhanced production of light olefins

Mohammad Ghashghaee^*
, Samira Shirvani
, Mehdi Ghambarian
, Søren Kegnæs

^*Corresponding author for this work

Department of Chemistry

Iran Polymer and Petrochemical Institute

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

Application of methanol as a coreactant in the atmospheric catalytic cracking of refinery fuel oil (abbreviated as the MFOCC process) over the H-ZSM-5 catalyst has been investigated for the first time with the aim to improve the olefin productivity of the heavy hydrocarbons and mitigate coke formation and catalyst deactivation. The results clearly proved the synergistic influence of cocracking in the MFOCC scenario. The integrated MFOCC process increased both light olefin (C₂⁼-C₄⁼) yield and gasoline (C₅-C₁₁) share of the liquid products to more than 36.7 and 78.7 wt %, respectively. Influence of contact time and temperature was also discussed.

Original language	English
Journal	Energy and Fuels
Volume	33
Issue number	6
Pages (from-to)	5761-5765
Number of pages	5
ISSN	0887-0624
DOIs	https://doi.org/10.1021/acs.energyfuels.9b00347
Publication status	Published - 2019

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@article{339cd33062c7462c8ece000cc14a9466,

title = "Synergistic coconversion of refinery fuel oil and methanol over H-ZSM-5 catalyst for enhanced production of light olefins",

abstract = "Application of methanol as a coreactant in the atmospheric catalytic cracking of refinery fuel oil (abbreviated as the MFOCC process) over the H-ZSM-5 catalyst has been investigated for the first time with the aim to improve the olefin productivity of the heavy hydrocarbons and mitigate coke formation and catalyst deactivation. The results clearly proved the synergistic influence of cocracking in the MFOCC scenario. The integrated MFOCC process increased both light olefin (C2=-C4=) yield and gasoline (C5-C11) share of the liquid products to more than 36.7 and 78.7 wt \%, respectively. Influence of contact time and temperature was also discussed.",

author = "Mohammad Ghashghaee and Samira Shirvani and Mehdi Ghambarian and S{\o}ren Kegn{\ae}s",

year = "2019",

doi = "10.1021/acs.energyfuels.9b00347",

language = "English",

volume = "33",

pages = "5761--5765",

journal = "Energy and Fuels",

issn = "0887-0624",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Synergistic coconversion of refinery fuel oil and methanol over H-ZSM-5 catalyst for enhanced production of light olefins

AU - Ghashghaee, Mohammad

AU - Shirvani, Samira

AU - Ghambarian, Mehdi

AU - Kegnæs, Søren

PY - 2019

Y1 - 2019

N2 - Application of methanol as a coreactant in the atmospheric catalytic cracking of refinery fuel oil (abbreviated as the MFOCC process) over the H-ZSM-5 catalyst has been investigated for the first time with the aim to improve the olefin productivity of the heavy hydrocarbons and mitigate coke formation and catalyst deactivation. The results clearly proved the synergistic influence of cocracking in the MFOCC scenario. The integrated MFOCC process increased both light olefin (C2=-C4=) yield and gasoline (C5-C11) share of the liquid products to more than 36.7 and 78.7 wt %, respectively. Influence of contact time and temperature was also discussed.

AB - Application of methanol as a coreactant in the atmospheric catalytic cracking of refinery fuel oil (abbreviated as the MFOCC process) over the H-ZSM-5 catalyst has been investigated for the first time with the aim to improve the olefin productivity of the heavy hydrocarbons and mitigate coke formation and catalyst deactivation. The results clearly proved the synergistic influence of cocracking in the MFOCC scenario. The integrated MFOCC process increased both light olefin (C2=-C4=) yield and gasoline (C5-C11) share of the liquid products to more than 36.7 and 78.7 wt %, respectively. Influence of contact time and temperature was also discussed.

U2 - 10.1021/acs.energyfuels.9b00347

DO - 10.1021/acs.energyfuels.9b00347

M3 - Journal article

AN - SCOPUS:85067951545

SN - 0887-0624

VL - 33

SP - 5761

EP - 5765

JO - Energy and Fuels

JF - Energy and Fuels

IS - 6

ER -

Synergistic coconversion of refinery fuel oil and methanol over H-ZSM-5 catalyst for enhanced production of light olefins

Abstract

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