Synchrotron X-Ray Study of Novel Crystalline-B Phases in Heptyloxybenzylidene-Heptylaniline (70.7)

J. Collet, L. B. Sorensen, P. S. Pershan, J. D. Litster, R. J. Birgeneau, Jens Aage Als-Nielsen

    Research output: Contribution to journalJournal articleResearchpeer-review

    Abstract

    This paper reports an x-ray diffraction study of structures and restacking transitions within the B phases of heptyloxybenzylidene-heptylaniline. The system evolves from a hexagonal close-packed structure, through intermediate orthorhombic and monoclinic phases, to a simple hexagonal structure. The monoclinic phase has a temperature-dependent shear which transforms the system from orthorhombic to hexagonal. The latter three phases exhibit a single-q⃗ sinusoidal modulation of the molecular layers.
    Original languageEnglish
    JournalPhysical Review Letters
    Volume49
    Issue number8
    Pages (from-to)553-556
    ISSN0031-9007
    DOIs
    Publication statusPublished - 1982

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