Surface chemistry in three dimensions: CO dissociation between two surfaces

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Abstract

Based on self-consistent density functional calculations it is shown that a new dissociation process for CO adsorbed on a Ru(0001) surface is made possible when the distance to a second Ru(0001) surface placed just above it is below some critical value. This '3D' process is more facile than the usual single surface ('2D') process because indirect adsorbate-adsorbate interactions in the transition state are absent in the '3D' case. The prospects for STM-induced single molecule chemistry and for '3D' catalysts are discussed. (C) 2000 Elsevier Science B.V. All rights reserved.
Original languageEnglish
JournalChemical Physics Letters
Volume322
Issue number5
Pages (from-to)307
ISSN0009-2614
DOIs
Publication statusPublished - 2000

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