Supported Rh-phosphine complex catalysts for continuous gas-phase decarbonylation of aldehydes.

Phillip Malcho; Eduardo J. Garcia-Suarez; Uffe Vie Mentzel; Christian Engelbrekt; Anders Riisager

doi:10.1039/c4dt01629g

Supported Rh-phosphine complex catalysts for continuous gas-phase decarbonylation of aldehydes.

Phillip Malcho
, Eduardo J. Garcia-Suarez
, Uffe Vie Mentzel
, Christian Engelbrekt
, Anders Riisager

Department of Chemistry

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

Heterogeneous silica supported rhodium-phosphine complex catalysts are employed for the first time in the catalytic decarbonylation of aldehydes in continuous gas-phase. The reaction protocol is exemplified for the decarbonylation of p-tolualdehyde to toluene and further extended to other aromatic and aliphatic aldehydes achieving excellent results in terms of both conversion and selectivity.

Original language	English
Journal	Dalton Transactions
Volume	43
Issue number	46
Pages (from-to)	17230-17235
ISSN	1477-9226
DOIs	https://doi.org/10.1039/c4dt01629g
Publication status	Published - 2014

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title = "Supported Rh-phosphine complex catalysts for continuous gas-phase decarbonylation of aldehydes.",

abstract = "Heterogeneous silica supported rhodium-phosphine complex catalysts are employed for the first time in the catalytic decarbonylation of aldehydes in continuous gas-phase. The reaction protocol is exemplified for the decarbonylation of p-tolualdehyde to toluene and further extended to other aromatic and aliphatic aldehydes achieving excellent results in terms of both conversion and selectivity.",

author = "Phillip Malcho and Garcia-Suarez, \{Eduardo J.\} and Mentzel, \{Uffe Vie\} and Christian Engelbrekt and Anders Riisager",

year = "2014",

doi = "10.1039/c4dt01629g",

language = "English",

volume = "43",

pages = "17230--17235",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "46",

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TY - JOUR

T1 - Supported Rh-phosphine complex catalysts for continuous gas-phase decarbonylation of aldehydes.

AU - Malcho, Phillip

AU - Garcia-Suarez, Eduardo J.

AU - Mentzel, Uffe Vie

AU - Engelbrekt, Christian

AU - Riisager, Anders

PY - 2014

Y1 - 2014

N2 - Heterogeneous silica supported rhodium-phosphine complex catalysts are employed for the first time in the catalytic decarbonylation of aldehydes in continuous gas-phase. The reaction protocol is exemplified for the decarbonylation of p-tolualdehyde to toluene and further extended to other aromatic and aliphatic aldehydes achieving excellent results in terms of both conversion and selectivity.

AB - Heterogeneous silica supported rhodium-phosphine complex catalysts are employed for the first time in the catalytic decarbonylation of aldehydes in continuous gas-phase. The reaction protocol is exemplified for the decarbonylation of p-tolualdehyde to toluene and further extended to other aromatic and aliphatic aldehydes achieving excellent results in terms of both conversion and selectivity.

U2 - 10.1039/c4dt01629g

DO - 10.1039/c4dt01629g

M3 - Journal article

C2 - 25333728

SN - 1477-9226

VL - 43

SP - 17230

EP - 17235

JO - Dalton Transactions

JF - Dalton Transactions

IS - 46

ER -

Supported Rh-phosphine complex catalysts for continuous gas-phase decarbonylation of aldehydes.

Abstract

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