Supported Ionic Liquid Phase (SILP) catalysis: An innovative concept for homogeneous catalysis in continuous fixed-bed reactors

Research output: Contribution to journalReview – Annual report year: 2006Researchpeer-review

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Supported Ionic Liquid Phase (SILP) catalysis : An innovative concept for homogeneous catalysis in continuous fixed-bed reactors. / Riisager, Anders; Fehrmann, Rasmus; Haumann, Marco; Wasserscheid, Peter.

In: European Journal of Inorganic Chemistry, No. 4, 2006, p. 695-706.

Research output: Contribution to journalReview – Annual report year: 2006Researchpeer-review

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@article{02298bc847ad44f29cfd0fac6ef85df9,
title = "Supported Ionic Liquid Phase (SILP) catalysis: An innovative concept for homogeneous catalysis in continuous fixed-bed reactors",
abstract = "Applications of ionic liquids to replace conventional solvents in homogeneous transition-metal catalysis have increased significantly during the last decade. Biphasic ionic liquid/organic liquid systems offer advantages with regard to product separation, catalyst stability, and recycling but utilise in the case of fast chemical reactions only a small amount of expensive ionic liquid and catalyst. The novel Supported Ionic Liquid Phase (SILP) catalysis concept overcomes these drawbacks and allows the use of fixed-bed reactors for continuous reactions. In this Microreview the SILP catalysis concept is surveyed by presenting results for the continuous gas-phase hydroformylation of propene, as a reaction example. (c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006.",
keywords = "Ionic liquids, Supported catalysts, Immobilisation, Homogeneous catalysis, Hydroformylation",
author = "Anders Riisager and Rasmus Fehrmann and Marco Haumann and Peter Wasserscheid",
year = "2006",
doi = "10.1002/ejic.200500872",
language = "English",
pages = "695--706",
journal = "European Journal of Inorganic Chemistry",
issn = "1434-1948",
publisher = "Wiley - V C H Verlag GmbH & Co. KGaA",
number = "4",

}

RIS

TY - JOUR

T1 - Supported Ionic Liquid Phase (SILP) catalysis

T2 - An innovative concept for homogeneous catalysis in continuous fixed-bed reactors

AU - Riisager, Anders

AU - Fehrmann, Rasmus

AU - Haumann, Marco

AU - Wasserscheid, Peter

PY - 2006

Y1 - 2006

N2 - Applications of ionic liquids to replace conventional solvents in homogeneous transition-metal catalysis have increased significantly during the last decade. Biphasic ionic liquid/organic liquid systems offer advantages with regard to product separation, catalyst stability, and recycling but utilise in the case of fast chemical reactions only a small amount of expensive ionic liquid and catalyst. The novel Supported Ionic Liquid Phase (SILP) catalysis concept overcomes these drawbacks and allows the use of fixed-bed reactors for continuous reactions. In this Microreview the SILP catalysis concept is surveyed by presenting results for the continuous gas-phase hydroformylation of propene, as a reaction example. (c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006.

AB - Applications of ionic liquids to replace conventional solvents in homogeneous transition-metal catalysis have increased significantly during the last decade. Biphasic ionic liquid/organic liquid systems offer advantages with regard to product separation, catalyst stability, and recycling but utilise in the case of fast chemical reactions only a small amount of expensive ionic liquid and catalyst. The novel Supported Ionic Liquid Phase (SILP) catalysis concept overcomes these drawbacks and allows the use of fixed-bed reactors for continuous reactions. In this Microreview the SILP catalysis concept is surveyed by presenting results for the continuous gas-phase hydroformylation of propene, as a reaction example. (c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006.

KW - Ionic liquids

KW - Supported catalysts

KW - Immobilisation

KW - Homogeneous catalysis

KW - Hydroformylation

U2 - 10.1002/ejic.200500872

DO - 10.1002/ejic.200500872

M3 - Review

SP - 695

EP - 706

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

SN - 1434-1948

IS - 4

ER -