242Pu as tracer for simultaneous determination of 237Np and 239,240Pu in environmental samples

Q.J. Chen, H. Dahlgaard, S.P. Nielsen, A. Aarkrog

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    Abstract

    A procedure has been developed using Pu-242 as tracer for simultaneous determination of Np-237 and Pu-239,Pu-240 in environmental samples. The validity of the method has been demonstrated by ICPMS and alpha-spectroscopy for up to 10 gram soil and sediment, seawater up to 200 litres. The paper describes a suitable chemical procedure for Np and Pu including a quantitative pre-concentration of neptunium and plutonium, preparation of Np4+ and Pu4+, NP(NO3)(6)(2-) and Pu(NO3)(6)(2-), The ratio of Np-237/Pu-242 (or Np-237/Pu-239) before and after the procedure has been determined using 10 g soil (free from Np and Pu) R-before/R-after = 1.004 +/- 3.3% (S.D n = 20) and 1 litre seawater R-before/R-after = 1.019+/-1.9% (S.D., n = 12). Results from the intercomparison samples LAEA-135, LAEA-381 and from environmental samples are presented.
    Original languageEnglish
    JournalJournal of Radioanalytical and Nuclear Chemistry
    Volume253
    Issue number3
    Pages (from-to)451-458
    ISSN0236-5731
    DOIs
    Publication statusPublished - 2002

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