Structural Tracking of a Bimolecular Reaction in Solution by Time-Resolved X-Ray Scattering

Kristoffer Haldrup, Morten Christensen, Marco Cammarata, Qingyu Kong, Michael Wulff, Simon O. Mariager, Klaus Bechgaard, Robert Feidenhans'l, Niels Harrit, Martin Meedom Nielsen

Research output: Contribution to journalJournal articleResearchpeer-review

Abstract

Molecular movies: Time-resolved X-ray scattering provides direct structural information on an electronically excited complex while it is formed in the bimolecular reaction between excited octahydrogen[tetrakis-μ-diphosphito-1κP:2κP′-diplatinate](4-) (PtPOP*) and thallium ions. In the exciplex one thallium(I) and two platinum(II) ions are found to be collinear.
Original languageEnglish
JournalAngewandte Chemie International Edition
Volume48
Issue number23
Pages (from-to)4180–4184
ISSN1433-7851
DOIs
Publication statusPublished - 2009
Externally publishedYes

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