Stability of the Gel Electrolyte PAN : EC : PC : LICF3SO3 towards Lithium

Kumudu Perera, M.A.K.L. Dissanayake, Steen Skaarup, K. West

Research output: Chapter in Book/Report/Conference proceedingArticle in proceedingsResearchpeer-review

Abstract

The stability of the gel electrolyte consisting of polyacrylonitrile (PAN), ethylene carbonate (EC), propylene carbonate (PC) and lithium trifluoromethanesulfonate (LiCF3SO3 – LiTF) towards metallic lithium was investigated using the time evolution of impedance plots. Symmetric cells of the form Li / PAN : EC : PC: LiTF / Li were assembled and impedance data were collected at room temperature for one week. A clear indication of growth of a resistive layer could be seen. The electrolyte resistance remained constant. The growth of the passivation layer became constant after first two days. These observations suggest that this gel electrolyte is suitable for use with metallic lithium.
Original languageEnglish
Title of host publicationSolid State Ionics: Advanced Materials for Emerging Technologies
EditorsB.V.R. Chowdari, M.A. Careem, M.A.K.L. Dissanayake, R.M.G. Rajapakse, V.A. Seneviratne
Place of PublicationSingapore
PublisherWorld Scientific
Publication date2006
Pages538-542
ISBN (Print)981-256-877-8
Publication statusPublished - 2006
Event10th Asian Conference on Solid State Ionics - Kandy, Sri Lanka
Duration: 12 Jun 200616 Jun 2006
Conference number: 10

Conference

Conference10th Asian Conference on Solid State Ionics
Number10
CountrySri Lanka
CityKandy
Period12/06/200616/06/2006

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