Spontaneous Breakup of Extended Monodisperse Polymer Melts

Henrik K. Rasmussen, Kaijia Yu

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Abstract

We apply continuum mechanical based, numerical modeling to study the dynamics of extended monodisperse polymer melts during the relaxation. The computations are within the ideas of the microstructural ‘‘interchain pressure’’ theory. The computations show a delayed necking resulting in a rupture, as a result of small initial sample imperfections. These ruptures agree with experimental observations.
Original languageEnglish
Article number126001
JournalPhysical Review Letters
Volume107
Number of pages4
ISSN0031-9007
DOIs
Publication statusPublished - 2011

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© American Physical Society

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