Solvated Positron Chemistry. The Reaction of Hydrated Positrons with Chloride Ions

O. E. Mogensen; V. P. Shantarovich

doi:10.1016/0301-0104(74)80037-6

Solvated Positron Chemistry. The Reaction of Hydrated Positrons with Chloride Ions

O. E. Mogensen, V. P. Shantarovich

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

The reaction of hydrated positrons (caq+ with cloride ions in aqueous solutions has been studied by means of positron annihilation angular correlation measurements. A rate constant of k = (2.5 ± 0.5) × 1010 M−1 s−1 was found. Probably the reacting positrons annihilated from an e+ Cl− bound state resulting in an angular correlation curve 8% narrower than for the hydrated positron. Carbontetrachloride in benzene seems to give similar, but smaller effect.

Original language	English
Journal	Chemical Physics
Volume	6
Issue number	1
Pages (from-to)	100-108
ISSN	0301-0104
DOIs	https://doi.org/10.1016/0301-0104(74)80037-6
Publication status	Published - 1974

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title = "Solvated Positron Chemistry. The Reaction of Hydrated Positrons with Chloride Ions",

abstract = "The reaction of hydrated positrons (caq+ with cloride ions in aqueous solutions has been studied by means of positron annihilation angular correlation measurements. A rate constant of k = (2.5 ± 0.5) × 1010 M−1 s−1 was found. Probably the reacting positrons annihilated from an e+ Cl− bound state resulting in an angular correlation curve 8% narrower than for the hydrated positron. Carbontetrachloride in benzene seems to give similar, but smaller effect.",

author = "Mogensen, {O. E.} and Shantarovich, {V. P.}",

year = "1974",

doi = "10.1016/0301-0104(74)80037-6",

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pages = "100--108",

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T1 - Solvated Positron Chemistry. The Reaction of Hydrated Positrons with Chloride Ions

AU - Mogensen, O. E.

AU - Shantarovich, V. P.

PY - 1974

Y1 - 1974

N2 - The reaction of hydrated positrons (caq+ with cloride ions in aqueous solutions has been studied by means of positron annihilation angular correlation measurements. A rate constant of k = (2.5 ± 0.5) × 1010 M−1 s−1 was found. Probably the reacting positrons annihilated from an e+ Cl− bound state resulting in an angular correlation curve 8% narrower than for the hydrated positron. Carbontetrachloride in benzene seems to give similar, but smaller effect.

AB - The reaction of hydrated positrons (caq+ with cloride ions in aqueous solutions has been studied by means of positron annihilation angular correlation measurements. A rate constant of k = (2.5 ± 0.5) × 1010 M−1 s−1 was found. Probably the reacting positrons annihilated from an e+ Cl− bound state resulting in an angular correlation curve 8% narrower than for the hydrated positron. Carbontetrachloride in benzene seems to give similar, but smaller effect.

U2 - 10.1016/0301-0104(74)80037-6

DO - 10.1016/0301-0104(74)80037-6

M3 - Journal article

SN - 0301-0104

VL - 6

SP - 100

EP - 108

JO - Chemical Physics

JF - Chemical Physics

IS - 1

ER -

Solvated Positron Chemistry. The Reaction of Hydrated Positrons with Chloride Ions

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