Abstract
The reaction of hydrated positrons (caq+ with cloride ions in aqueous solutions has been studied by means of positron annihilation angular correlation measurements. A rate constant of k = (2.5 ± 0.5) × 1010 M−1 s−1 was found. Probably the reacting positrons annihilated from an e+ Cl− bound state resulting in an angular correlation curve 8% narrower than for the hydrated positron. Carbontetrachloride in benzene seems to give similar, but smaller effect.
Original language | English |
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Journal | Chemical Physics |
Volume | 6 |
Issue number | 1 |
Pages (from-to) | 100-108 |
ISSN | 0301-0104 |
DOIs | |
Publication status | Published - 1974 |