Simple Method to Determine the Partition Coefficient of Naphthenic Acid in Oil/Water

Anders Bitsch-Larsen; Simon Ivar Andersen

doi:10.1021/je800287f

Simple Method to Determine the Partition Coefficient of Naphthenic Acid in Oil/Water

Anders Bitsch-Larsen
, Simon Ivar Andersen

Department of Chemical and Biochemical Engineering

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

The partition coefficient for technical grade naphthenic acid in water/n-decane at 295 K has been determined (K-wo = 2.1 center dot 10(-4)) using a simple experimental technique with large extraction volumes (0.09 m(3) of water). Furthermore, nonequilibrium values at different pH values are presented. Analysis of the acid content in the oil phase was conducted by FT-IR and colormetric titration and found to be equivalent.

Original language	English
Journal	Journal of Chemical and Engineering Data
Volume	53
Issue number	10
Pages (from-to)	2272-2274
ISSN	0021-9568
DOIs	https://doi.org/10.1021/je800287f
Publication status	Published - 2008

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title = "Simple Method to Determine the Partition Coefficient of Naphthenic Acid in Oil/Water",

abstract = "The partition coefficient for technical grade naphthenic acid in water/n-decane at 295 K has been determined (K-wo = 2.1 center dot 10(-4)) using a simple experimental technique with large extraction volumes (0.09 m(3) of water). Furthermore, nonequilibrium values at different pH values are presented. Analysis of the acid content in the oil phase was conducted by FT-IR and colormetric titration and found to be equivalent.",

author = "Anders Bitsch-Larsen and Andersen, \{Simon Ivar\}",

year = "2008",

doi = "10.1021/je800287f",

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publisher = "American Chemical Society",

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AU - Andersen, Simon Ivar

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N2 - The partition coefficient for technical grade naphthenic acid in water/n-decane at 295 K has been determined (K-wo = 2.1 center dot 10(-4)) using a simple experimental technique with large extraction volumes (0.09 m(3) of water). Furthermore, nonequilibrium values at different pH values are presented. Analysis of the acid content in the oil phase was conducted by FT-IR and colormetric titration and found to be equivalent.

AB - The partition coefficient for technical grade naphthenic acid in water/n-decane at 295 K has been determined (K-wo = 2.1 center dot 10(-4)) using a simple experimental technique with large extraction volumes (0.09 m(3) of water). Furthermore, nonequilibrium values at different pH values are presented. Analysis of the acid content in the oil phase was conducted by FT-IR and colormetric titration and found to be equivalent.

U2 - 10.1021/je800287f

DO - 10.1021/je800287f

M3 - Journal article

SN - 0021-9568

VL - 53

SP - 2272

EP - 2274

JO - Journal of Chemical and Engineering Data

JF - Journal of Chemical and Engineering Data

IS - 10

ER -

Simple Method to Determine the Partition Coefficient of Naphthenic Acid in Oil/Water

Abstract

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