Silicone-modified graphene oxide fillers via the Piers-Rubinsztajn reaction

Jianfeng Zhang; Shuai Liang; Liyun Yu; Anne Ladegaard Skov; Hussein M. Etmimi; Peter E. Mallon; Alex Adronov; Michael A. Brook

doi:10.1002/pola.28112

Silicone-modified graphene oxide fillers via the Piers-Rubinsztajn reaction

Jianfeng Zhang, Shuai Liang, Liyun Yu, Anne Ladegaard Skov, Hussein M. Etmimi, Peter E. Mallon, Alex Adronov, Michael A. Brook

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

While graphene or graphene oxide can make significantimprovements in the properties of a wide variety of polymericmaterials, their incorporation can be challenged byincompatibility with the polymeric matrix. The modification ofgraphene oxide with silicones or silanes using the Piers-Rubinsztajn reaction improves dispersibility in nonpolar materials,including organic solvents and silicone pre-elastomers. Ahigh loading (up to 10 wt %) of modified graphene oxide insilicone elastomers could be achieved, which resulted inenhanced mechanical performance and reduced gas permeability.

Original language	English
Journal	Journal of Polymer Science. Part A, Polymer Chemistry
Volume	54
Issue number	15
Pages (from-to)	2379–2385
ISSN	0887-624X
DOIs	https://doi.org/10.1002/pola.28112
Publication status	Published - 2016

Keywords

Elastomers
Fillers
Graphene oxide
Piers-Rubinsztajn reaction
Reductive silylation
Reinforced silicone elastomers
Silicones

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10.1002/pola.28112

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title = "Silicone-modified graphene oxide fillers via the Piers-Rubinsztajn reaction",

abstract = "While graphene or graphene oxide can make significantimprovements in the properties of a wide variety of polymericmaterials, their incorporation can be challenged byincompatibility with the polymeric matrix. The modification ofgraphene oxide with silicones or silanes using the Piers-Rubinsztajn reaction improves dispersibility in nonpolar materials,including organic solvents and silicone pre-elastomers. Ahigh loading (up to 10 wt %) of modified graphene oxide insilicone elastomers could be achieved, which resulted inenhanced mechanical performance and reduced gas permeability.",

keywords = "Elastomers, Fillers, Graphene oxide, Piers-Rubinsztajn reaction, Reductive silylation, Reinforced silicone elastomers, Silicones",

author = "Jianfeng Zhang and Shuai Liang and Liyun Yu and Skov, {Anne Ladegaard} and Etmimi, {Hussein M.} and Mallon, {Peter E.} and Alex Adronov and Brook, {Michael A.}",

year = "2016",

doi = "10.1002/pola.28112",

language = "English",

volume = "54",

pages = "2379–2385 ",

journal = "Journal of Polymer Science. Part A, Polymer Chemistry",

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T1 - Silicone-modified graphene oxide fillers via the Piers-Rubinsztajn reaction

AU - Zhang, Jianfeng

AU - Liang, Shuai

AU - Yu, Liyun

AU - Skov, Anne Ladegaard

AU - Etmimi, Hussein M.

AU - Mallon, Peter E.

AU - Adronov, Alex

AU - Brook, Michael A.

PY - 2016

Y1 - 2016

N2 - While graphene or graphene oxide can make significantimprovements in the properties of a wide variety of polymericmaterials, their incorporation can be challenged byincompatibility with the polymeric matrix. The modification ofgraphene oxide with silicones or silanes using the Piers-Rubinsztajn reaction improves dispersibility in nonpolar materials,including organic solvents and silicone pre-elastomers. Ahigh loading (up to 10 wt %) of modified graphene oxide insilicone elastomers could be achieved, which resulted inenhanced mechanical performance and reduced gas permeability.

AB - While graphene or graphene oxide can make significantimprovements in the properties of a wide variety of polymericmaterials, their incorporation can be challenged byincompatibility with the polymeric matrix. The modification ofgraphene oxide with silicones or silanes using the Piers-Rubinsztajn reaction improves dispersibility in nonpolar materials,including organic solvents and silicone pre-elastomers. Ahigh loading (up to 10 wt %) of modified graphene oxide insilicone elastomers could be achieved, which resulted inenhanced mechanical performance and reduced gas permeability.

KW - Elastomers

KW - Fillers

KW - Graphene oxide

KW - Piers-Rubinsztajn reaction

KW - Reductive silylation

KW - Reinforced silicone elastomers

KW - Silicones

U2 - 10.1002/pola.28112

DO - 10.1002/pola.28112

M3 - Journal article

SN - 0887-624X

VL - 54

SP - 2379

EP - 2385

JO - Journal of Polymer Science. Part A, Polymer Chemistry

JF - Journal of Polymer Science. Part A, Polymer Chemistry

IS - 15

ER -

Silicone-modified graphene oxide fillers via the Piers-Rubinsztajn reaction

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Keywords

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