Shape distortion and thermo-mechanical properties of SOFC components from green tape to sintering body

Francesca Teocoli, De Wei Ni, Tesfaye Tadesse Molla, Karen Brodersen, Severine Ramousse, Henrik Lund Frandsen, Vincenzo Esposito

Research output: Contribution to conferenceConference abstract for conferenceResearchpeer-review

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Abstract

Sintering in ceramic materials is a critical process, especially when these are shaped as multilayer. From the green stage to the densification, the effects of organic additives removal, solid state diffusive phenomena, and either differential expansion or contraction of the layers can have critical effect on the final shape leading also failure, delamination etc. In this work, a tape-cast bi-layer structure for CGO and YSZ-(Sc) was studied during the thermal processing from debinding to the sintering. The bilayered samples undergo to several phenomena of shape instabilities and deformation due to binder burn out, differential shrinkage behavior and to a potential interfacial reaction between the two materials. To analyze the phenomena, shrinkage of SOFC components single layers and bilayered samples were measured insitu by optical dilatometer. The densification mismatch stress, due to the strain rate difference between materials, was calculated using Cai’s model. Camber (curvature) development for in situ co-firing of a bi-layer ceramic green tape has been investigated. Analysis of shape evolution from green to sintered body can be carried out by the thermo-mechanical analysis techniques.
Original languageEnglish
Publication date2012
Number of pages1
Publication statusPublished - 2012
EventNordic Conference on Ceramic and Glass Technology - DTU Risø Campus, Roskilde, Denmark
Duration: 6 Dec 20127 Dec 2012

Conference

ConferenceNordic Conference on Ceramic and Glass Technology
LocationDTU Risø Campus
CountryDenmark
CityRoskilde
Period06/12/201207/12/2012

Cite this

Teocoli, F., Ni, D. W., Tadesse Molla, T., Brodersen, K., Ramousse, S., Frandsen, H. L., & Esposito, V. (2012). Shape distortion and thermo-mechanical properties of SOFC components from green tape to sintering body. Abstract from Nordic Conference on Ceramic and Glass Technology, Roskilde, Denmark.
Teocoli, Francesca ; Ni, De Wei ; Tadesse Molla, Tesfaye ; Brodersen, Karen ; Ramousse, Severine ; Frandsen, Henrik Lund ; Esposito, Vincenzo. / Shape distortion and thermo-mechanical properties of SOFC components from green tape to sintering body. Abstract from Nordic Conference on Ceramic and Glass Technology, Roskilde, Denmark.1 p.
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title = "Shape distortion and thermo-mechanical properties of SOFC components from green tape to sintering body",
abstract = "Sintering in ceramic materials is a critical process, especially when these are shaped as multilayer. From the green stage to the densification, the effects of organic additives removal, solid state diffusive phenomena, and either differential expansion or contraction of the layers can have critical effect on the final shape leading also failure, delamination etc. In this work, a tape-cast bi-layer structure for CGO and YSZ-(Sc) was studied during the thermal processing from debinding to the sintering. The bilayered samples undergo to several phenomena of shape instabilities and deformation due to binder burn out, differential shrinkage behavior and to a potential interfacial reaction between the two materials. To analyze the phenomena, shrinkage of SOFC components single layers and bilayered samples were measured insitu by optical dilatometer. The densification mismatch stress, due to the strain rate difference between materials, was calculated using Cai’s model. Camber (curvature) development for in situ co-firing of a bi-layer ceramic green tape has been investigated. Analysis of shape evolution from green to sintered body can be carried out by the thermo-mechanical analysis techniques.",
author = "Francesca Teocoli and Ni, {De Wei} and {Tadesse Molla}, Tesfaye and Karen Brodersen and Severine Ramousse and Frandsen, {Henrik Lund} and Vincenzo Esposito",
year = "2012",
language = "English",
note = "Nordic Conference on Ceramic and Glass Technology ; Conference date: 06-12-2012 Through 07-12-2012",

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Teocoli, F, Ni, DW, Tadesse Molla, T, Brodersen, K, Ramousse, S, Frandsen, HL & Esposito, V 2012, 'Shape distortion and thermo-mechanical properties of SOFC components from green tape to sintering body' Nordic Conference on Ceramic and Glass Technology, Roskilde, Denmark, 06/12/2012 - 07/12/2012, .

Shape distortion and thermo-mechanical properties of SOFC components from green tape to sintering body. / Teocoli, Francesca; Ni, De Wei; Tadesse Molla, Tesfaye; Brodersen, Karen; Ramousse, Severine; Frandsen, Henrik Lund; Esposito, Vincenzo.

2012. Abstract from Nordic Conference on Ceramic and Glass Technology, Roskilde, Denmark.

Research output: Contribution to conferenceConference abstract for conferenceResearchpeer-review

TY - ABST

T1 - Shape distortion and thermo-mechanical properties of SOFC components from green tape to sintering body

AU - Teocoli, Francesca

AU - Ni, De Wei

AU - Tadesse Molla, Tesfaye

AU - Brodersen, Karen

AU - Ramousse, Severine

AU - Frandsen, Henrik Lund

AU - Esposito, Vincenzo

PY - 2012

Y1 - 2012

N2 - Sintering in ceramic materials is a critical process, especially when these are shaped as multilayer. From the green stage to the densification, the effects of organic additives removal, solid state diffusive phenomena, and either differential expansion or contraction of the layers can have critical effect on the final shape leading also failure, delamination etc. In this work, a tape-cast bi-layer structure for CGO and YSZ-(Sc) was studied during the thermal processing from debinding to the sintering. The bilayered samples undergo to several phenomena of shape instabilities and deformation due to binder burn out, differential shrinkage behavior and to a potential interfacial reaction between the two materials. To analyze the phenomena, shrinkage of SOFC components single layers and bilayered samples were measured insitu by optical dilatometer. The densification mismatch stress, due to the strain rate difference between materials, was calculated using Cai’s model. Camber (curvature) development for in situ co-firing of a bi-layer ceramic green tape has been investigated. Analysis of shape evolution from green to sintered body can be carried out by the thermo-mechanical analysis techniques.

AB - Sintering in ceramic materials is a critical process, especially when these are shaped as multilayer. From the green stage to the densification, the effects of organic additives removal, solid state diffusive phenomena, and either differential expansion or contraction of the layers can have critical effect on the final shape leading also failure, delamination etc. In this work, a tape-cast bi-layer structure for CGO and YSZ-(Sc) was studied during the thermal processing from debinding to the sintering. The bilayered samples undergo to several phenomena of shape instabilities and deformation due to binder burn out, differential shrinkage behavior and to a potential interfacial reaction between the two materials. To analyze the phenomena, shrinkage of SOFC components single layers and bilayered samples were measured insitu by optical dilatometer. The densification mismatch stress, due to the strain rate difference between materials, was calculated using Cai’s model. Camber (curvature) development for in situ co-firing of a bi-layer ceramic green tape has been investigated. Analysis of shape evolution from green to sintered body can be carried out by the thermo-mechanical analysis techniques.

M3 - Conference abstract for conference

ER -

Teocoli F, Ni DW, Tadesse Molla T, Brodersen K, Ramousse S, Frandsen HL et al. Shape distortion and thermo-mechanical properties of SOFC components from green tape to sintering body. 2012. Abstract from Nordic Conference on Ceramic and Glass Technology, Roskilde, Denmark.