Sequential electrodialytic recovery of phosphorus from low-temperature gasification ashes of chemically precipitated sewage sludge

Raimon Parés Viader, Pernille Erland Jensen, Lisbeth M. Ottosen, Jesper Ahrenfeldt, Henrik Hauggaard-Nielsen

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Abstract

Phosphorus recycling from secondary materials like sewage sludge ashes offers an alternative to mining of phosphates from primary resources and a mean to counteract the current phosphorous rock depletion concern. A separation of P from the bulk ash is normally required, due to its low plant availability and the presence of heavy metals. Previously, more than 80% of P was recovered from incineration sewage sludge ashes using a two-compartment electrodialytic cell. In contrast, the recovery was below 30% for ashes from low-temperature gasification using the same setup. The low recovery was due to a high presence of Al- and Fe(III)-P bindings. In the present study, an electrodialytic process combining sequentially a pair of two-compartment cells allowed a recovery of up to 70% of phosphorus from these ashes. The use of a second cell, where the ash was suspended in an alkaline solution, allowed the P solubilisation from aluminium and ferric phosphates. In addition, P was separated from most metals as they became insoluble under the prevailing chemical environment. The obtained ratio of Al, Fe, Mg and most heavy metals to P was comparable to wet process phosphoric acid. Therefore, this sequential process was found to be suitable to recycle P and potentially use it in the production of common fertilizers like diammonium phosphate. 
Original languageEnglish
JournalWaste Management
Volume60
Pages (from-to)211–218
ISSN0956-053x
DOIs
Publication statusPublished - 2017

Keywords

  • Electrodialysis
  • Heavy metals
  • Iron phosphates
  • Low-temperature gasification
  • Phosphorus
  • Sewage sludge ash

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