Abstract
We present a semiclassical model for laser fragmentation of polyatomic molecules in an intense laser field. The model assumes a few active bonds which may break due to the interaction with the field and a quantum heat bath. The quantum heat bath consists of a set of harmonic oscillators (normal modes) coupled together through the Coriolis interaction. The model may also be used to study the dynamics of unimolecular decomposition.
Original language | English |
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Journal | Chemical Physics |
Volume | 119 |
Issue number | 2-3 |
Pages (from-to) | 205-219 |
ISSN | 0301-0104 |
DOIs | |
Publication status | Published - 1988 |
Externally published | Yes |