Selective side-chain oxidation of alkyl aromatic compounds catalyzed by cerium modified silver catalysts

Matthias Josef Beier, Bjoern Schimmoeller, Thomas Willum Hansen, Jens Enevold Thaulov Andersen, Sotiris E. Pratsinis, Jan-Dierk Grunwaldt

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Silver supported on silica effectively catalyzes the aerobic side-chain oxidation of alkyl aromatic compounds under solvent-free conditions. Toluene, p-xylene, ethylbenzene and cumene were investigated as model substrates. Typically, the reaction was performed at ambient pressure; only for toluene an elevated pressure was required. Carboxylic acids, such as benzoic acid or p-toluic acid, additionally increased the reaction rate while CeO2 could act both as a promoter and an inhibitor depending on the substrate and the reaction conditions. Silver catalysts were prepared both by standard impregnation and flame spray pyrolysis. Addition of a Ce precursor to the FSP catalyst resulted in significantly smaller silver particles. Ce-doped FSP catalysts in general exhibited a superior catalytic performance with TONs up to 2000 except for cumene oxidation that appeared to proceed mainly by homogeneous catalysis. In addition, flame-made catalysts were more stable against silver leaching compared to the impregnated catalysts. The structure of the silver catalysts was studied in detail both by X-ray absorption spectroscopy and transmission electron microscopy suggesting metallic silver to be required for catalytic activity. Catalytic studies point to a radical mechanism which differs depending on the type of substrate.
Original languageEnglish
JournalJournal of Molecular Catalysis A: Chemical
Pages (from-to)40-49
Publication statusPublished - 2010


  • Silver catalysis
  • Homogeneous vs. heterogeneous catalysis
  • Flame spray pyrolysis
  • p-Xylene
  • Selective aerobic oxidation


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