Selective formic acid dehydrogenation at low temperature over a RuO2/COF pre-catalyst synthesized on the gram scale

Liliana P. L. Gonçalves; David Benjamin Christensen; Maria Meledina; Laura M. Salonen; Dmitri Y. Petrovykh; Enrique Carbó-Argibay; Juliana P. S. Sousa; O. Salomé G. P. Soares; M. Fernando R. Pereira; Søren Kegnæs; Yury V. Kolen'ko

doi:10.1039/d0cy00145g

Selective formic acid dehydrogenation at low temperature over a RuO₂/COF pre-catalyst synthesized on the gram scale

Liliana P. L. Gonçalves, David Benjamin Christensen^*, Maria Meledina, Laura M. Salonen, Dmitri Y. Petrovykh, Enrique Carbó-Argibay, Juliana P. S. Sousa, O. Salomé G. P. Soares, M. Fernando R. Pereira, Søren Kegnæs, Yury V. Kolen'ko

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

A pre-catalyst, consisting of RuO₂ nanoparticles and clusters anchored on TpBD-Me₂ COF, was synthesized. During catalytic formic acid dehydrogenation, RuO₂ undergoes in situ reduction to metallic Ru, forming an active and selective catalyst, which outperforms the commercial Ru–C catalyst. The chemical structure of the COF supporting material is maintained during stability testing.

Original language	English
Journal	Catalysis Science and Technology
Volume	10
Pages (from-to)	1991-1995
ISSN	2044-4753
DOIs	https://doi.org/10.1039/d0cy00145g
Publication status	Published - 2020

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Gonçalves, L. P. L., Christensen, D. B., Meledina, M., Salonen, L. M., Petrovykh, D. Y., Carbó-Argibay, E., Sousa, J. P. S., Soares, O. S. G. P., Pereira, M. F. R., Kegnæs, S., & Kolen'ko, Y. V. (2020). Selective formic acid dehydrogenation at low temperature over a RuO₂/COF pre-catalyst synthesized on the gram scale. Catalysis Science and Technology, 10, 1991-1995. https://doi.org/10.1039/d0cy00145g

Gonçalves, Liliana P. L. ; Christensen, David Benjamin ; Meledina, Maria ; Salonen, Laura M. ; Petrovykh, Dmitri Y. ; Carbó-Argibay, Enrique ; Sousa, Juliana P. S. ; Soares, O. Salomé G. P. ; Pereira, M. Fernando R. ; Kegnæs, Søren ; Kolen'ko, Yury V. / Selective formic acid dehydrogenation at low temperature over a RuO₂/COF pre-catalyst synthesized on the gram scale. In: Catalysis Science and Technology. 2020 ; Vol. 10. pp. 1991-1995.

@article{53ea29f21b534c878b75ff163eabb793,

title = "Selective formic acid dehydrogenation at low temperature over a RuO2/COF pre-catalyst synthesized on the gram scale",

abstract = "A pre-catalyst, consisting of RuO2 nanoparticles and clusters anchored on TpBD-Me2 COF, was synthesized. During catalytic formic acid dehydrogenation, RuO2 undergoes in situ reduction to metallic Ru, forming an active and selective catalyst, which outperforms the commercial Ru–C catalyst. The chemical structure of the COF supporting material is maintained during stability testing.",

author = "Gon{\c c}alves, {Liliana P. L.} and Christensen, {David Benjamin} and Maria Meledina and Salonen, {Laura M.} and Petrovykh, {Dmitri Y.} and Enrique Carb{\'o}-Argibay and Sousa, {Juliana P. S.} and Soares, {O. Salom{\'e} G. P.} and Pereira, {M. Fernando R.} and S{\o}ren Kegn{\ae}s and Kolen'ko, {Yury V.}",

year = "2020",

doi = "10.1039/d0cy00145g",

language = "English",

volume = "10",

pages = "1991--1995",

journal = "Catalysis Science & Technology",

issn = "2044-4753",

publisher = "Royal Society of Chemistry",

}

Gonçalves, LPL, Christensen, DB, Meledina, M, Salonen, LM, Petrovykh, DY, Carbó-Argibay, E, Sousa, JPS, Soares, OSGP, Pereira, MFR, Kegnæs, S & Kolen'ko, YV 2020, 'Selective formic acid dehydrogenation at low temperature over a RuO₂/COF pre-catalyst synthesized on the gram scale', Catalysis Science and Technology, vol. 10, pp. 1991-1995. https://doi.org/10.1039/d0cy00145g

Selective formic acid dehydrogenation at low temperature over a RuO₂/COF pre-catalyst synthesized on the gram scale. / Gonçalves, Liliana P. L.; Christensen, David Benjamin; Meledina, Maria; Salonen, Laura M.; Petrovykh, Dmitri Y.; Carbó-Argibay, Enrique; Sousa, Juliana P. S.; Soares, O. Salomé G. P.; Pereira, M. Fernando R.; Kegnæs, Søren; Kolen'ko, Yury V.

In: Catalysis Science and Technology, Vol. 10, 2020, p. 1991-1995.

Research output: Contribution to journal › Journal article › Research › peer-review

TY - JOUR

T1 - Selective formic acid dehydrogenation at low temperature over a RuO2/COF pre-catalyst synthesized on the gram scale

AU - Gonçalves, Liliana P. L.

AU - Christensen, David Benjamin

AU - Meledina, Maria

AU - Salonen, Laura M.

AU - Petrovykh, Dmitri Y.

AU - Carbó-Argibay, Enrique

AU - Sousa, Juliana P. S.

AU - Soares, O. Salomé G. P.

AU - Pereira, M. Fernando R.

AU - Kegnæs, Søren

AU - Kolen'ko, Yury V.

PY - 2020

Y1 - 2020

N2 - A pre-catalyst, consisting of RuO2 nanoparticles and clusters anchored on TpBD-Me2 COF, was synthesized. During catalytic formic acid dehydrogenation, RuO2 undergoes in situ reduction to metallic Ru, forming an active and selective catalyst, which outperforms the commercial Ru–C catalyst. The chemical structure of the COF supporting material is maintained during stability testing.

AB - A pre-catalyst, consisting of RuO2 nanoparticles and clusters anchored on TpBD-Me2 COF, was synthesized. During catalytic formic acid dehydrogenation, RuO2 undergoes in situ reduction to metallic Ru, forming an active and selective catalyst, which outperforms the commercial Ru–C catalyst. The chemical structure of the COF supporting material is maintained during stability testing.

U2 - 10.1039/d0cy00145g

DO - 10.1039/d0cy00145g

M3 - Journal article

VL - 10

SP - 1991

EP - 1995

JO - Catalysis Science & Technology

JF - Catalysis Science & Technology

SN - 2044-4753

ER -