Selective formic acid dehydrogenation at low temperature over a RuO2/COF pre-catalyst synthesized on the gram scale

Liliana P. L. Gonçalves, David Benjamin Christensen*, Maria Meledina, Laura M. Salonen, Dmitri Y. Petrovykh, Enrique Carbó-Argibay, Juliana P. S. Sousa, O. Salomé G. P. Soares, M. Fernando R. Pereira, Søren Kegnæs, Yury V. Kolen'ko

*Corresponding author for this work

Research output: Contribution to journalJournal articleResearchpeer-review

Abstract

A pre-catalyst, consisting of RuO2 nanoparticles and clusters anchored on TpBD-Me2 COF, was synthesized. During catalytic formic acid dehydrogenation, RuO2 undergoes in situ reduction to metallic Ru, forming an active and selective catalyst, which outperforms the commercial Ru–C catalyst. The chemical structure of the COF supporting material is maintained during stability testing.
Original languageEnglish
JournalCatalysis Science and Technology
Volume10
Pages (from-to)1991-1995
ISSN2044-4753
DOIs
Publication statusPublished - 2020

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