Rhodium Catalyzed Decarbonylation

Eduardo José Garcia Suárez, Klara Kahr, Anders Riisager

Research output: Chapter in Book/Report/Conference proceedingBook chapterResearchpeer-review

Abstract

Rhodium catalyzed decarbonylation has developed significantly over the last 50 years and resulted in a wide range of reported catalyst systems and reaction protocols. Besides experimental data, literature also includes mechanistic studies incorporating Hammett methods, analysis of kinetic isotope effects as well as computational studies of model systems, which give an indication of the scope of the process. In this chapter, fundamental applications of Rh-catalyzed decarbonylation reactions are surveyed and discussed, including cross-coupling reactions, tandem reactions, and alternative methodologies for process intensification.
Original languageEnglish
Title of host publicationRhodium Catalysis
Number of pages21
Publication date2017
Pages145-165
ISBN (Print)978-3-319-66663-1
ISBN (Electronic)978-3-319-66665-5
DOIs
Publication statusPublished - 2017
SeriesTopics in Organometallic Chemistry
Volume61
ISSN1436-6002

Keywords

  • Chemistry
  • Organometallic Chemistry
  • Catalysis
  • Physical Chemistry
  • Aldehydes
  • Aryl-aryl coupling
  • Continuous-flow systems
  • Cross-coupling
  • Decarbonylation
  • Heck coupling
  • Ionic liquids
  • Oppenauer oxidation
  • Pauson–Khand
  • Rhodium
  • Sugars
  • Tandem reaction

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