Resonant infrared pulsed laser deposition of thin biodegradable polymer films

D.M. Bubb; B. Toftmann; R.F. Haglund Jr.; J.S. Horwitz; M.R. Papantonakis; R.A. McGill; P.W. Wu; D.B. Chrisey

doi:10.1007/s003390101010

Resonant infrared pulsed laser deposition of thin biodegradable polymer films

D.M. Bubb, B. Toftmann, R.F. Haglund Jr., J.S. Horwitz, M.R. Papantonakis, R.A. McGill, P.W. Wu, D.B. Chrisey

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

Thin films of the biodegradable polymer poly(DL-lactide-co-glycolide) (PLGA) were deposited using resonant infrared pulsed laser deposition (RIR-PLD). The output of a free-electron laser was focused onto a solid target of the polymer, and the films were deposited using 2.90 (resonant with O-H stretch) and 3.40 (C-H) mum light at macropulse fluences of 7.8 and 6.7 J/cm(2), respectively. Under these conditions, a 0.5-mum thick film can be grown in less than 5 min. Film structure was determined from infrared absorbance measurements and gel permeation chromatography (GPC). While the infrared absorbance spectrum of the films is nearly identical with that of the native polymer, the average molecular weight of the films is a little less than half that of the starting material. Potential strategies for defeating this mass change are discussed.

Original language	English
Journal	Applied Physics A: Materials Science & Processing
Volume	74
Issue number	1
Pages (from-to)	123-125
ISSN	0947-8396
DOIs	https://doi.org/10.1007/s003390101010
Publication status	Published - 2002

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10.1007/s003390101010

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@article{e1e06446f8a34aeba816ad83574e1715,

title = "Resonant infrared pulsed laser deposition of thin biodegradable polymer films",

abstract = "Thin films of the biodegradable polymer poly(DL-lactide-co-glycolide) (PLGA) were deposited using resonant infrared pulsed laser deposition (RIR-PLD). The output of a free-electron laser was focused onto a solid target of the polymer, and the films were deposited using 2.90 (resonant with O-H stretch) and 3.40 (C-H) mum light at macropulse fluences of 7.8 and 6.7 J/cm(2), respectively. Under these conditions, a 0.5-mum thick film can be grown in less than 5 min. Film structure was determined from infrared absorbance measurements and gel permeation chromatography (GPC). While the infrared absorbance spectrum of the films is nearly identical with that of the native polymer, the average molecular weight of the films is a little less than half that of the starting material. Potential strategies for defeating this mass change are discussed. ",

keywords = "6-I optik",

author = "D.M. Bubb and B. Toftmann and {Haglund Jr.}, R.F. and J.S. Horwitz and M.R. Papantonakis and R.A. McGill and P.W. Wu and D.B. Chrisey",

year = "2002",

doi = "10.1007/s003390101010",

language = "English",

volume = "74",

pages = "123--125",

journal = "Applied Physics A: Materials Science & Processing",

issn = "0947-8396",

publisher = "Springer",

number = "1",

}

Resonant infrared pulsed laser deposition of thin biodegradable polymer films. / Bubb, D.M.; Toftmann, B.; Haglund Jr., R.F.; Horwitz, J.S.; Papantonakis, M.R.; McGill, R.A.; Wu, P.W.; Chrisey, D.B.

In: Applied Physics A: Materials Science & Processing, Vol. 74, No. 1, 2002, p. 123-125.

Research output: Contribution to journal › Journal article › Research › peer-review

TY - JOUR

T1 - Resonant infrared pulsed laser deposition of thin biodegradable polymer films

AU - Bubb, D.M.

AU - Toftmann, B.

AU - Haglund Jr., R.F.

AU - Horwitz, J.S.

AU - Papantonakis, M.R.

AU - McGill, R.A.

AU - Wu, P.W.

AU - Chrisey, D.B.

PY - 2002

Y1 - 2002

N2 - Thin films of the biodegradable polymer poly(DL-lactide-co-glycolide) (PLGA) were deposited using resonant infrared pulsed laser deposition (RIR-PLD). The output of a free-electron laser was focused onto a solid target of the polymer, and the films were deposited using 2.90 (resonant with O-H stretch) and 3.40 (C-H) mum light at macropulse fluences of 7.8 and 6.7 J/cm(2), respectively. Under these conditions, a 0.5-mum thick film can be grown in less than 5 min. Film structure was determined from infrared absorbance measurements and gel permeation chromatography (GPC). While the infrared absorbance spectrum of the films is nearly identical with that of the native polymer, the average molecular weight of the films is a little less than half that of the starting material. Potential strategies for defeating this mass change are discussed.

AB - Thin films of the biodegradable polymer poly(DL-lactide-co-glycolide) (PLGA) were deposited using resonant infrared pulsed laser deposition (RIR-PLD). The output of a free-electron laser was focused onto a solid target of the polymer, and the films were deposited using 2.90 (resonant with O-H stretch) and 3.40 (C-H) mum light at macropulse fluences of 7.8 and 6.7 J/cm(2), respectively. Under these conditions, a 0.5-mum thick film can be grown in less than 5 min. Film structure was determined from infrared absorbance measurements and gel permeation chromatography (GPC). While the infrared absorbance spectrum of the films is nearly identical with that of the native polymer, the average molecular weight of the films is a little less than half that of the starting material. Potential strategies for defeating this mass change are discussed.

KW - 6-I optik

U2 - 10.1007/s003390101010

DO - 10.1007/s003390101010

M3 - Journal article

VL - 74

SP - 123

EP - 125

JO - Applied Physics A: Materials Science & Processing

JF - Applied Physics A: Materials Science & Processing

SN - 0947-8396

IS - 1

ER -

Resonant infrared pulsed laser deposition of thin biodegradable polymer films

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