Resonance Raman study of benzyl radical

F.W. Langkilde, K. Bajdor, R. Wilbrandt

    Research output: Contribution to journalJournal articleResearch

    Abstract

    Time-resolved resonance Raman spectra are obtained of benzyl radicals created by laser flash photolysis of benzylchloride and diphenylacetone in solution. The spectra are obtained in resonance with the intense 2 2A2-1 B-2(2) transition of benzyl. The strong Raman bands are assigned to totally symmetric a1 modes. The remaining observed bands are tentatively assigned to fundamental modes of b1, a2, and b2 symmetry, and to overtones and combinations. The resonance Raman spectra are found to be quite different from previous fluorescence spectra of benzyl, and the origins of these differences are discussed.
    Original languageEnglish
    JournalChemical Physics Letters
    Volume193
    Issue number1-3
    Pages (from-to)169-175
    ISSN0009-2614
    DOIs
    Publication statusPublished - 1992

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