Reactive kinetics of carbon dioxide loaded aqueous blend of 2-amino-2-ethyl-1,3-propanediol and piperazine using a pressure drop method

Research output: Contribution to journalJournal article – Annual report year: 2019Researchpeer-review

DOI

  • Author: Ullah, Sami

    King Khalid University, Saudi Arabia

  • Author: Suleman, Humbul

    CERE – Center for Energy Ressources Engineering, Department of Chemical and Biochemical Engineering, Technical University of Denmark, Søltofts Plads, 2800, Kgs. Lyngby, Denmark

  • Author: Tahir, Muhammad Suleman

    University of Gujrat, Pakistan

  • Author: Sagir, Muhammad

    University of Gujrat, Pakistan

  • Author: Muhammad, Shabbir

    King Khalid University, Saudi Arabia

  • Author: Al-Sehemi, Abdullah G.

    King Khalid University, Saudi Arabia

  • Author: Zafar, Masood-ur-Rauf

    FC Institute of Engineering and Fertilizer Research, Pakistan

  • Author: Kareem, Firas A. Abdul

    Universiti Teknologi Petronas, Malaysia

  • Author: Maulud, Abdulhalim Shah

    Universiti Teknologi Petronas, Malaysia

  • Author: Bustam, Mohamad Azmi

    Universiti Teknologi Petronas, Malaysia

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In this study, a new pressure drop method has been used to investigate the kinetics of carbon dioxide reaction with aqueous blend of 2‐amino‐2‐ethyl‐1,3‐propanediol (AEPD) with piperazine (PZ). The blending of a small amount of PZ with AEPD has a significant effect on the observed rate constant, kobs. It was observed that kobs values of the blend increased more than twice than the summation of kobs values of individual alkanolamines. The reaction kinetics in this study were modeled by assuming a termolecular mechanism. The addition of 0.1 mol/L of PZ to 1 mol/L AEPD exhibited an observed rate constant, kobs of 8824.1 s−1, which is comparable to other alkanolamine mixtures. Hence, PZ/AEPD mixtures can be potentially used for rapid carbon dioxide capture.
Original languageEnglish
JournalInternational Journal of Chemical Kinetics
Volume51
Issue number4
Pages (from-to)291-298
ISSN0538-8066
DOIs
Publication statusPublished - 2019
CitationsWeb of Science® Times Cited: No match on DOI

    Research areas

  • Alkanolamines, Carbon dioxide, Kinetic modeling, Pressure drop method, Reaction kinetics

ID: 166791684