Reactions of H2O3 in the pulse-irradiated Fe(II)-O2 system

Knud Sehested, Erling Bjergbakke, O. Lang Rasmussen, H. Fricke

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    G(Fe(III)] is measured in pulse-irradiated O2-saturated solutions of 20 to 160 μMFe(II), at the p H's 0.46, 1.51, and 2.74 H2SO4 and HClO4 and with dose rates between 1 and 8 krad/1 μsec pulse. Based on homogeneous kinetics, the results are interpreted by a system of 18 reactions. The formation of the hydrogen sesquioxide H2O3 as an intermediate in the reaction OH+HO2→H2O3→H2O+O 2 is confirmed
    Original languageEnglish
    JournalJournal of Chemical Physics
    Issue number8
    Pages (from-to)3159-3166
    Publication statusPublished - 1969


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