Rate of reaction of dimethylmercury with oxygen atoms in the gas phase

Helge Egsgaard

doi:10.1016/0009-2614(86)85176-4

Rate of reaction of dimethylmercury with oxygen atoms in the gas phase

Helge Egsgaard

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

The rate constant for the reaction of atomic oxygen (O(3P)) with dimethylmercury has been measured at room temperature at a pressure of about 1 Torr using a fast flow system with electron paramagnetic resonance and mass spectrometric detection. Some reaction products were identified. The rate constant found is (2.5 ± 0.2) × 10−11 cm3 molecule−1 s−1.

Original language	English
Journal	Chemical Physics Letters
Volume	125
Issue number	4
Pages (from-to)	378-382
ISSN	0009-2614
DOIs	https://doi.org/10.1016/0009-2614(86)85176-4
Publication status	Published - 1986

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title = "Rate of reaction of dimethylmercury with oxygen atoms in the gas phase",

abstract = "The rate constant for the reaction of atomic oxygen (O(3P)) with dimethylmercury has been measured at room temperature at a pressure of about 1 Torr using a fast flow system with electron paramagnetic resonance and mass spectrometric detection. Some reaction products were identified. The rate constant found is (2.5 ± 0.2) × 10−11 cm3 molecule−1 s−1.",

author = "Helge Egsgaard",

year = "1986",

doi = "10.1016/0009-2614(86)85176-4",

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pages = "378--382",

journal = "Chemical Physics Letters",

issn = "0009-2614",

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number = "4",

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T1 - Rate of reaction of dimethylmercury with oxygen atoms in the gas phase

AU - Egsgaard, Helge

PY - 1986

Y1 - 1986

N2 - The rate constant for the reaction of atomic oxygen (O(3P)) with dimethylmercury has been measured at room temperature at a pressure of about 1 Torr using a fast flow system with electron paramagnetic resonance and mass spectrometric detection. Some reaction products were identified. The rate constant found is (2.5 ± 0.2) × 10−11 cm3 molecule−1 s−1.

AB - The rate constant for the reaction of atomic oxygen (O(3P)) with dimethylmercury has been measured at room temperature at a pressure of about 1 Torr using a fast flow system with electron paramagnetic resonance and mass spectrometric detection. Some reaction products were identified. The rate constant found is (2.5 ± 0.2) × 10−11 cm3 molecule−1 s−1.

U2 - 10.1016/0009-2614(86)85176-4

DO - 10.1016/0009-2614(86)85176-4

M3 - Journal article

SN - 0009-2614

VL - 125

SP - 378

EP - 382

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 4

ER -

Rate of reaction of dimethylmercury with oxygen atoms in the gas phase

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