Quality assurance of fluorescence peak intensities in EDXRF analysis of environmental samples

L. Højslet Christensen, K. Heydorn

    Research output: Contribution to journalJournal articleResearchpeer-review

    Abstract

    A quality assurance methodology based on the Analysis of Precision was applied to results obtained by EDXRF. It was found that statistical control could be achieved in the processing of X-ray spectra with the program MicroSAMPO and an optimized Covell program, but not with a conventional Gaussian fitting program. Final results were consistent with an a priori precision of approximately 1% from the sample preparation stage, and no significant uncertainty could be attributed to the backscatter/fundamental parameter approach to the quantification. The method under investigation was found suitable for the analysis of environmental samples from chromium-contaminated grounds.
    Original languageEnglish
    JournalNuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment
    Volume299
    Issue number1-3
    Pages (from-to)562-566
    ISSN0168-9002
    DOIs
    Publication statusPublished - 1990

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