Pulsed radiofrequency glow discharge time-of-flight mass spectrometry for molecular depth profiling of polymer-based films

Nunzio Tuccitto, Lara Lobo, Agnes Tempez, Ivan Delfanti, Patrick Chapon, Stela Canulescu, Nerea Bordel, Johann Michler, Antonino Licciardello

Research output: Contribution to journalJournal articleResearchpeer-review


We demonstrate the potential of an innovative technique, pulsed radiofrequency glow discharge time-of-flight mass spectrometry, for the molecular depth profiling of polymer materials. The technique benefits from the presence, in the afterglow of the pulsed glow discharge, of fragment ions that can be related to the structures of the polymers under study. Thin films of different polymers (PMMA, PET, PAMS, PS) were successfully profiled with retention of molecular information along the profile. Multilayered structures of the above polymers were also profiled, and it was possible to discriminate among layers having similar elemental composition but different polymer structure. Copyright (C) 2009 John Wiley & Sons, Ltd.
Original languageEnglish
JournalRapid Communications in Mass Spectrometry
Issue number5
Pages (from-to)549-556
Publication statusPublished - 2009
Externally publishedYes

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