Pulsed laser deposition of chalcogenide sulfides from multi- and single-component targets: the non-stoichiometric material transfer

Jørgen Schou; Mungunshagai Ganskukh; Rebecca Bolt Ettlinger; Andrea Carlo Cazzaniga; Maarja  Grossberg; Marit  Kauk-Kuusik; Stela Canulescu

doi:10.1007/s00339-017-1475-3

Pulsed laser deposition of chalcogenide sulfides from multi- and single-component targets: the non-stoichiometric material transfer

Jørgen Schou^*, Mungunshagai Ganskukh, Rebecca Bolt Ettlinger, Andrea Carlo Cazzaniga, Maarja Grossberg, Marit Kauk-Kuusik, Stela Canulescu

^*Corresponding author for this work

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

The mass transfer from target to films is incongruent for chalcogenide sulfides in contrast to the expectations of pulsed laser deposition (PLD) as a stoichiometric film growth process. Films produced from a CZTS (Cu₂ZnSnS₄) multi-component target have no Cu below a fluence threshold of 0.2 J/cm², and the Cu content is also very low at low fluence from a single-component target. Above this threshold, the Cu content in the films increases almost linearly up to a value above the stoichiometric value, while the ratio of the concentration of the other metals Zn to Sn (Zn/Sn) remains constant. Films of a similar material CTS (Cu₂SnS₃) have been produced by PLD from a CTS target and exhibits a similar trend in the same fluence region. The results are discussed on the basis of solid-state data and the existing data from the literature.

Original language	English
Article number	78
Journal	Applied Physics A: Materials Science & Processing
Volume	124
Issue number	1
ISSN	0947-8396
DOIs	https://doi.org/10.1007/s00339-017-1475-3
Publication status	Published - 2018

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@article{bf976e788e1a4faf9a51b490d8b6e160,

title = "Pulsed laser deposition of chalcogenide sulfides from multi- and single-component targets: the non-stoichiometric material transfer",

abstract = "The mass transfer from target to films is incongruent for chalcogenide sulfides in contrast to the expectations of pulsed laser deposition (PLD) as a stoichiometric film growth process. Films produced from a CZTS (Cu2ZnSnS4) multi-component target have no Cu below a fluence threshold of 0.2 J/cm2, and the Cu content is also very low at low fluence from a single-component target. Above this threshold, the Cu content in the films increases almost linearly up to a value above the stoichiometric value, while the ratio of the concentration of the other metals Zn to Sn (Zn/Sn) remains constant. Films of a similar material CTS (Cu2SnS3) have been produced by PLD from a CTS target and exhibits a similar trend in the same fluence region. The results are discussed on the basis of solid-state data and the existing data from the literature.",

author = "J{\o}rgen Schou and Mungunshagai Ganskukh and Ettlinger, {Rebecca Bolt} and Cazzaniga, {Andrea Carlo} and Maarja Grossberg and Marit Kauk-Kuusik and Stela Canulescu",

year = "2018",

doi = "10.1007/s00339-017-1475-3",

language = "English",

volume = "124",

journal = "Applied Physics A: Materials Science & Processing",

issn = "0947-8396",

publisher = "Springer",

number = "1",

}

Pulsed laser deposition of chalcogenide sulfides from multi- and single-component targets: the non-stoichiometric material transfer. / Schou, Jørgen; Ganskukh, Mungunshagai; Ettlinger, Rebecca Bolt; Cazzaniga, Andrea Carlo; Grossberg, Maarja ; Kauk-Kuusik, Marit ; Canulescu, Stela.

In: Applied Physics A: Materials Science & Processing, Vol. 124, No. 1, 78, 2018.

Research output: Contribution to journal › Journal article › Research › peer-review

TY - JOUR

T1 - Pulsed laser deposition of chalcogenide sulfides from multi- and single-component targets: the non-stoichiometric material transfer

AU - Schou, Jørgen

AU - Ganskukh, Mungunshagai

AU - Ettlinger, Rebecca Bolt

AU - Cazzaniga, Andrea Carlo

AU - Grossberg, Maarja

AU - Kauk-Kuusik, Marit

AU - Canulescu, Stela

PY - 2018

Y1 - 2018

N2 - The mass transfer from target to films is incongruent for chalcogenide sulfides in contrast to the expectations of pulsed laser deposition (PLD) as a stoichiometric film growth process. Films produced from a CZTS (Cu2ZnSnS4) multi-component target have no Cu below a fluence threshold of 0.2 J/cm2, and the Cu content is also very low at low fluence from a single-component target. Above this threshold, the Cu content in the films increases almost linearly up to a value above the stoichiometric value, while the ratio of the concentration of the other metals Zn to Sn (Zn/Sn) remains constant. Films of a similar material CTS (Cu2SnS3) have been produced by PLD from a CTS target and exhibits a similar trend in the same fluence region. The results are discussed on the basis of solid-state data and the existing data from the literature.

AB - The mass transfer from target to films is incongruent for chalcogenide sulfides in contrast to the expectations of pulsed laser deposition (PLD) as a stoichiometric film growth process. Films produced from a CZTS (Cu2ZnSnS4) multi-component target have no Cu below a fluence threshold of 0.2 J/cm2, and the Cu content is also very low at low fluence from a single-component target. Above this threshold, the Cu content in the films increases almost linearly up to a value above the stoichiometric value, while the ratio of the concentration of the other metals Zn to Sn (Zn/Sn) remains constant. Films of a similar material CTS (Cu2SnS3) have been produced by PLD from a CTS target and exhibits a similar trend in the same fluence region. The results are discussed on the basis of solid-state data and the existing data from the literature.

U2 - 10.1007/s00339-017-1475-3

DO - 10.1007/s00339-017-1475-3

M3 - Journal article

VL - 124

JO - Applied Physics A: Materials Science & Processing

JF - Applied Physics A: Materials Science & Processing

SN - 0947-8396

IS - 1

M1 - 78

ER -