Pulse-Radiolysis of Aqueous KBrO4 Solutions

K. J. Olsen, Knud Sehested, L.H. Appelman

    Research output: Contribution to journalJournal articleResearchpeer-review

    Abstract

    Pulse-radiolysis of aqueous KBrO4 solutions show that BrO−4 reacts with e−aq by the reaction BrO−4 + e−aq → BrO−3 + O−. keaq + BrO−4 = (7.0 ± 0.7) × 109 M−1 sec−1. The reactions between BrO−4 and H, OH and O− are slow. The rate constants for these reactions are less than 107 M−1 sec−1.
    Original languageEnglish
    JournalChemical Physics Letters
    Volume19
    Issue number2
    Pages (from-to)213-214
    ISSN0009-2614
    Publication statusPublished - 1973

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